| 320343-67-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 320343-67-7
• 化学式: C₃₇H₄₂O₇
• 分子量: 598.736
• InChiKey: UNCBYYAJPRHOFX-LPYGTTGFSA-N

反应信息

• 作为反应物：
  描述：

  在 potassium carbonate 、 pyridinium chlorochromate 作用下， 以 甲醇 、 1,2-二氯乙烷 为溶剂， 反应 1.5h， 生成
  参考文献：
  名称：

  Synthesis of 3-Deoxy-α-d-manno-oct-2-ulosonic Acid Glycoside (Kdo) and Its 2-Deoxy Analogue:  A Horner−Emmons Approach

  摘要：

  [GRAPHICS]A very simple and potentially valuable synthetic approach to 3-deoxy-alpha-D-manno-oct-2-ulosonic acid glycoside is described. The key reaction in the synthesis is the construction of ketene dithioacetal from the corresponding 2-deoxy-D-manno-heptono-1,5-lactone and 1,3-dithianyl anion. The synthesis ends with a tandem oxidative hydrolysis of the dithianyl group/glycosylation process.

  DOI：

  10.1021/ol990931j
• 作为产物：
  描述：

  在 吡啶 、 三乙基硅烷 、 9-borabicyclo[3.3.1]nonane dimer 、 potassium hydride 、 三氟乙酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 9.0h， 生成
  参考文献：
  名称：

  Synthesis of 3-Deoxy-α-d-manno-oct-2-ulosonic Acid Glycoside (Kdo) and Its 2-Deoxy Analogue:  A Horner−Emmons Approach

  摘要：

  [GRAPHICS]A very simple and potentially valuable synthetic approach to 3-deoxy-alpha-D-manno-oct-2-ulosonic acid glycoside is described. The key reaction in the synthesis is the construction of ketene dithioacetal from the corresponding 2-deoxy-D-manno-heptono-1,5-lactone and 1,3-dithianyl anion. The synthesis ends with a tandem oxidative hydrolysis of the dithianyl group/glycosylation process.

  DOI：

  10.1021/ol990931j