2,6-dimethylcyclohex-1-ene-1-carboxylic acid | 854720-13-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2,6-dimethylcyclohex-1-ene-1-carboxylic acid
• 英文别名: 2,6-dimethyl-cyclohex-1-enecarboxylic acid；2.6-Dimethyl-Δ¹-tetrahydrobenzoesaeure；2,6-Dimethyl-cyclohex-1-encarbonsaeure；Δ¹-Tetrahydro-vic.-m-xylylsaeure；2,6-Dimethylcyclohexene-1-carboxylic acid
• CAS: 854720-13-1
• 化学式: C₉H₁₄O₂
• 分子量: 154.209
• InChiKey: MZLGUOPHBBZXMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,6-dimethylcyclohex-1-ene-1-carboxylic acid 在 氯仿 、 alkaline solution 、 溴 作用下， 生成 2,6-二甲基-环己-1,5-二烯羧酸
  参考文献：
  名称：

  Hufferd; Noyes, Journal of the American Chemical Society, 1921, vol. 43, p. 928

  摘要：

  DOI：
• 作为产物：
  描述：

  2,6-二甲基苯甲酸 在 氢氧化钾 、 戊醇 、 溴 、 sodium 作用下， 生成 2,6-dimethylcyclohex-1-ene-1-carboxylic acid
  参考文献：
  名称：

  Noyes, American Chemical Journal, 1899, vol. 22, p. 3

  摘要：

  DOI：

文献信息

• Palladium-Catalyzed Visible-Light-Driven Carboxylation of Aryl and Alkenyl Triflates by Using Photoredox Catalysts
  作者：Katsuya Shimomaki、Tomoya Nakajima、Joaquim Caner、Naoyuki Toriumi、Nobuharu Iwasawa

  DOI：10.1021/acs.orglett.9b01340

  日期：2019.6.21

  A visible-light-driven carboxylation of aryl and alkenyl triflates with CO2 is developed by using a combination of Pd and photoredox catalysts. This reaction proceeds under mild conditions and can be applied to a wide range of substrates including acyclic alkenyl triflates.

  通过使用Pd和光氧化还原催化剂的组合，可见光驱动的芳基和烯基三氟甲磺酸酯与CO 2的羧化反应。该反应在温和的条件下进行，可用于多种底物，包括无环烯基三氟甲磺酸酯。
• NOVEL PLANT GROWTH REGULATORS AND METHODS OF USING SAME
  申请人：Duke University

  公开号：EP3458592A1

  公开（公告）日：2019-03-27
• Novel Plant Growth Regulators and Methods of Using Same
  申请人：Duke University

  公开号：US20190289849A1

  公开（公告）日：2019-09-26

  This disclosure relates to methods of regulating growth in a plant. Specifically, the methods of the disclosure regulate growth of the plant by administration of a composition comprising an effective amount of one or more apocarotenoids to the plant, its part, or the seed.
• Compositions and Methods for Modulating Root Growth
  申请人：DUKE UNIVERSITY

  公开号：US20220000103A1

  公开（公告）日：2022-01-06

  This disclosure relates to methods of regulating growth in a plant. Specifically, the methods of the disclosure regulate growth of the plant by administration of a composition comprising an effective amount of one or more apocarotenoids to the plant, its part, or the seed.
• [EN] NOVEL PLANT GROWTH REGULATORS AND METHODS OF USING SAME<br/>[FR] NOUVEAUX RÉGULATEURS DE CROISSANCE VÉGÉTALE ET LEURS PROCÉDÉS D'UTILISATION
  申请人：UNIV DUKE

  公开号：WO2017201410A1

  公开（公告）日：2017-11-23

  This disclosure relates to methods of regulating growth in a plant. Specifically, the methods of the disclosure regulate growth of the plant by administration of a composition comprising an effective amount of one or more apocarotenoids to the plant, its part, or the seed.