[Cu((2,5-dimethylphenyl)-pyridin-2-ylmethylene-amine)2]ClO4 | 921622-58-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Cu((2,5-dimethylphenyl)-pyridin-2-ylmethylene-amine)2]ClO4
• CAS: 921622-58-4
• 化学式: C₂₈H₂₈CuN₄*ClO₄
• 分子量: 583.554
• InChiKey: QOEMUJCVUCRHKH-QUIZRFNZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(2,5-dimethylphenyl)-1-(pyridin-2-yl)methanimine 、 tetrakis(acetonitrile)copper(I) perchlorate 以 乙腈 为溶剂， 以89%的产率得到[Cu((2,5-dimethylphenyl)-pyridin-2-ylmethylene-amine)2]ClO4
  参考文献：
  名称：

  Synthesis, spectral characterization, properties and structures of copper(I) complexes containing novel bidentate iminopyridine ligands

  摘要：

  Four new ligands, (4-methyl-phenyl)-pyridin-2-ylmethylene-amine (A), (2,3-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (B), (2,4-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (C) and (2,5-dimethyl-phenyl)-pyridin-2-ylmethylene-amine (D), and their corresponding copper(I) complexes, [Cu(A)(2)]ClO4 (1a), [Cu(B)(2)]ClO4 (1b), [Cu(C)(2)]ClO4 (1c), [Cu(D)(2)]ClO4 (1d), [Cu(A)(PPh3)(2)]ClO4 (2a), [Cu(B)(PPh3)(2)]ClO4 (2b), [Cu(C)(PPh3)(2)]ClO4 (2c) and [Cu(D)(PPh3)(2)]ClO4 (2d), have been synthesized and characterized by CHN analyses, H-1 and C-13 NMR, IR and UV-Vis spectroscopy. The crystal structures of [Cu(B)(2)]ClO4 (1b), [Cu(C)(2)]ClO4 (1c) and [Cu(A)(PPh3)(2)]ClO4 center dot 1/2CH(3)CN (2a) were determined from single crystal X-ray diffraction. The coordination polyhedron about the copper(I) center in the three complexes is best described as a distorted tetrahedron. A quasireversible redox behavior is observed for the complexes. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.08.011