硬脂酰胺基丙基吗啉 | 55852-13-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 硬脂酰胺基丙基吗啉
• 中文别名: 硬脂酰胺丙基吗啉
• 英文名称: N-(3-morpholinopropyl) stearamide
• 英文别名: Stearamidopropyl morpholine；N-(3-morpholin-4-ylpropyl)octadecanamide
• CAS: 55852-13-6
• 化学式: C₂₅H₅₀N₂O₂
• 分子量: 410.684
• InChiKey: DIHCYFIQOLPTQW-UHFFFAOYSA-N

物化性质

• 熔点：
  59-61 °C
• 沸点：
  554.6±35.0 °C(Predicted)
• 密度：
  0.921±0.06 g/cm3(Predicted)
• LogP：
  7.541 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  29
• 可旋转键数：
  20
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.96
• 拓扑面积：
  41.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-(3-氨丙基)吗啉 、 硬脂酸 在 nano sulfated-TiO₂ 作用下， 115.0 ℃ 、101.33 kPa 条件下， 反应 1.0h， 以98%的产率得到硬脂酰胺基丙基吗啉
  参考文献：
  名称：

  Nano Sulfated Titania as Solid Acid Catalyst in Direct Synthesis of Fatty Acid Amides

  摘要：

  Nanosized sulfated titania was prepared by a sol gel hydrothermal process. X-ray diffraction (XRD), transmission electron, and scanning electron micrographs (TEM and SEM), FT-IR specific surface area, and BET N(2) adsorption were employed to characterize the properties of the synthesized sulfated TiO(2). The results indicate that both anatase and rutile TiO(2) are obtainable. This prepared sulfated titania showed high catalytic activity in direct amidation of fatty acids as well as benzoic acids with various amines under solvent-free conditions.

  DOI：

  10.1021/jo2002769

文献信息

• Nano Sulfated Titania as Solid Acid Catalyst in Direct Synthesis of Fatty Acid Amides
  作者：Mona Hosseini-Sarvari、Esmat Sodagar、Mohammad Mahdi Doroodmand

  DOI：10.1021/jo2002769

  日期：2011.4.15

  Nanosized sulfated titania was prepared by a sol gel hydrothermal process. X-ray diffraction (XRD), transmission electron, and scanning electron micrographs (TEM and SEM), FT-IR specific surface area, and BET N(2) adsorption were employed to characterize the properties of the synthesized sulfated TiO(2). The results indicate that both anatase and rutile TiO(2) are obtainable. This prepared sulfated titania showed high catalytic activity in direct amidation of fatty acids as well as benzoic acids with various amines under solvent-free conditions.