N-<1-Methyl-2-oxo-propyl>-acrylsaeureamid | 10324-92-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-<1-Methyl-2-oxo-propyl>-acrylsaeureamid
• 英文别名: N-(1-Methyl-2-oxo-propyl)-acrylsaeureamid；N-(3-oxobutan-2-yl)prop-2-enamide
• CAS: 10324-92-2
• 化学式: C₇H₁₁NO₂
• mdl: MFCD19222847
• 分子量: 141.17
• InChiKey: OHWATYQUBHZCAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.428
• 拓扑面积：
  46.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-acryloyl alanine 在 吡啶 、 乙酸酐 作用下， 生成 N-<1-Methyl-2-oxo-propyl>-acrylsaeureamid
  参考文献：
  名称：

  Synthesis of N-[1-(1-substituted 2-oxopropyl)]acrylamides and -methylacrylamides. Isolation and some reactions of intermediates of the Dakin-West reaction

  摘要：

  DOI：

  10.1021/jo01288a039

文献信息

• Aqueous based fire foam compositions containing hydrocarbyl sulfide terminated oligomer stabilizers
  申请人：CIBA-GEIGY AG

  公开号：EP0083312A1

  公开（公告）日：1983-07-06

  This invention relates to aqueous based fire fighting foams containing a stabilizing amount of an oligomer of the formula wherein R1 is an oleophilic aryl, araliphatic, aliphatic or cyclo-aliphatic group having up to 25 carbon atoms; E is a direct bond, or an organic covalently bonded divalent linking group, n is 0, 1 or 2, [M1] is a hydrophilic acrylamido monomer unit, [M2] is a copolymerizable non-acrylamido hydrophilic monomer unit, [M3] is a copolymerizable hydrophobic monomer unit, the average of the sum of x, y and z is between about 3 and about 500, andis between 1 and about 0.5. These stabilizing oligomer additives in aqueous based fire fighting foams improve foam expansion, foam drainage and fire extinguishing times.

  本发明涉及一种水基灭火泡沫，该泡沫含有稳定量的式中低聚物 其中 R1 是亲油芳基、脂肪族、脂肪族或环脂肪族基团，具有多达 25 个碳原子；E是直接键或有机共价键二价连接基团，n是0、1或2，[M1]是亲水性丙烯酰胺基单体单元，[M2]是可共聚的非丙烯酰胺基亲水性单体单元，[M3]是可共聚的疏水性单体单元，x、y和z之和的平均值在约3和约500之间，且在1和约0之间。5.水基灭火泡沫中的这些稳定低聚物添加剂可改善泡沫膨胀、泡沫排出和灭火时间。
• Graft copolymer and process for producing the same
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0490269A1

  公开（公告）日：1992-06-17

  There is provided a process for producing a styrenic graft copolymer which comprises coplymerizing a styrenic monomer and a styrenic monomer having a hydrocarbon radical with an unsaturated bond in the presence of a catalyst comprising as primary ingredient (A) a transition metal compound and (B) a contact product of an organoaluminum compound and a condensation agent or (C) a compound which produces an ionic complex by reacting with the above-mentioned transition metal compound and subsequently graft polymerizing an ethylenically unsaturated monomer onto the resultant styrenic copolymer. The above-described styrenic graft copolymer is greatly improved in terms of compatibility, adhesivity, coatability and wettability while preserving heat resistance and chemical resistance thereof, and thus effective as a variety of constructional materials and compatibilizing agents. Furthermore, the composition or multi-layer material comprising the above-mentioned styrenic graft copolymer is widely utilized in a variety of application field including film, sheet, especially stampable sheet, container, packaging material, automobile parts, electrical and electronic parts, etc.

  提供了一种生产苯乙烯接枝共聚物的工艺，该工艺包括在催化剂存在下，使苯乙烯单体和具有不饱和键烃基的苯乙烯单体共聚，催化剂的主要成分包括(A)过渡金属化合物和(B)有机铝化合物与缩合剂的接触产物或(C)通过与上述过渡金属化合物反应产生离子络合物的化合物，然后将乙烯基不饱和单体接枝聚合到生成的苯乙烯共聚物上。上述过渡金属化合物反应生成离子络合物的化合物，然后将乙烯不饱和单体接枝聚合到生成的苯乙烯共聚物上。 上述苯乙烯接枝共聚物在保持其耐热性和耐化学性的同时，在相容性、粘合性、涂覆性和润湿性方面得到了极大的改善，因此可以有效地用作各种建筑材料和相容剂。此外，由上述苯乙烯接枝共聚物组成的组合物或多层材料可广泛应用于各种应用领域，包括薄膜、片材，尤其是可冲压片材、容器、包装材料、汽车零件、电子电气零件等。
• Cross-linkable, electrically conductive composition, electric conductor and process for forming the same
  申请人：NITTO CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0837112A2

  公开（公告）日：1998-04-22

  An anticorrosive composition comprising (a') an acidic group-containing, self-doping type soluble, electrically conducting polymer.

  一种防腐组合物，包含 (a') 一种含酸性基团、自掺杂型可溶性导电聚合物。
• CROSS-LINKABLE CONDUCTIVE COMPOSITION, CONDUCTOR, AND PROCESS FOR FORMING THE SAME
  申请人：NITTO CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0844284A1

  公开（公告）日：1998-05-27

  The first of this invention is a cross-linkable, electrically conductive composition comprising (a) a soluble, electrically conducting polymer having a sulfonic acid group and/or a carboxyl group and (b) a compound having at least two functional groups capable of reacting with the sulfonic acid group and/or carboxyl group of the soluble, electrically conducting polymer (a).

  本发明的第一种是一种可交联导电组合物，它包括：(a) 具有磺酸基和/或羧基的可溶性导电聚合物；(b) 具有至少两个能与可溶性导电聚合物 (a) 的磺酸基和/或羧基反应的官能团的化合物。
• Process for producing styrenic copolymer
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0505972B1

  公开（公告）日：1997-06-11