申请人:KYOTO UNIVERSITY
公开号:US20160096910A1
公开(公告)日:2016-04-07
Conjugated diene polymer comprising at least a conjugated diene monomer unit, the conjugated diene polymer has a number-average molecular weight (Mn) in terms of polystyrene of 1,000 to 1,000,000, a ratio (Mw/Mn) of a weight-average molecular weight (Mw) to the number-average molecular weight (Mn) of lower than 2.0 and the polymer bears a halogen atom at a terminal of the polymer chain. Method for producing the conjugated diene polymer comprises subjecting a monomer containing at least a conjugated diene to living radical polymerization using a polymerization initiator comprising a halogenocyclopentadienyl triorganophosphine η
2
-olefin ruthenium complex represented by formula (6) (and an organic halide.
共轭二烯聚合物至少包含一个共轭二烯单体单元,该共轭二烯聚合物的聚合度数平均分子量(Mn)以聚苯乙烯为单位介于1,000至1,000,000之间,重均分子量(Mw)与数均分子量(Mn)的比值小于2.0,并且该聚合物在聚合物链的末端带有卤素原子。生产该共轭二烯聚合物的方法包括使用聚合引发剂,其中该聚合引发剂包括由式(6)表示的卤代环戊二烯基三有机膦η2-烯烃钌配合物(以及有机卤素),对至少含有一个共轭二烯的单体进行活性自由基聚合。