2,3,6-Trimethoxy-phenanthren-9,10-dicarbonsaeure-dimethylester | 95938-84-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,3,6-Trimethoxy-phenanthren-9,10-dicarbonsaeure-dimethylester
• 英文别名: 2,3,6-trimethoxy-phenanthrene-9,10-dicarboxylic acid dimethyl ester
• CAS: 95938-84-4
• 化学式: C₂₁H₂₀O₇
• 分子量: 384.386
• InChiKey: AFAOFFFUGRYBPJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 生成 2,3,6-Trimethoxy-phenanthren-9,10-dicarbonsaeure-dimethylester
  参考文献：
  名称：

  Govindachari et al., Chemistry and Industry, 1959, p. 950

  摘要：

  DOI：

文献信息

• Chemical examination of Tylophora asthmatica—V
  作者：T.R. Govindachari、B.R. Pai、I.S. Ragade、S. Rajappa、N. Viswanathan

  DOI：10.1016/s0040-4020(01)92178-7

  日期：1961.1

  Tylophorinine, the minor alkaloid of Tylophora asthmatica, has been oxidized to yield 2,3,6-trimethoxyphenanthrene-9,10-dicarboxylic acid. A synthesis of the corresponding imide has been achieved. Desoxytylophorinine, obtained by hydrogenolysis of the alkaloid, has been synthesized. These results in conjunction with other degradation experiments have enabled the assignment of the structure XIV to tylophorinine

  tylophorinine，哮喘的Tylophora哮喘的次要生物碱，已被氧化生成2,3,6-三甲氧基菲-9,10-二羧酸。已经实现了相应酰亚胺的合成。已经合成了通过生物碱的氢解获得的脱氧酪氨酸。这些结果与其他降解实验相结合，已使结构XIV可归属于酪氨酸。