3-(2,3-dihydroxypropoxy)-propanenitrile | 13196-68-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 3-(2,3-dihydroxypropoxy)-propanenitrile
• 英文别名: 3-(2,3-Dihydroxypropoxy)propanenitrile
• CAS: 13196-68-4
• 化学式: C₆H₁₁NO₃
• 分子量: 145.158
• InChiKey: KGDWESXNUZVRQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.5
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  73.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  丙烯腈 、 甘油 在 sodium hydroxide 作用下， 反应 3.0h， 以28%的产率得到3-(2,3-dihydroxypropoxy)-propanenitrile
  参考文献：
  名称：

  Free-solvent Michael addition of glycerol to acrylic compounds

  摘要：

  生物基甘油通过丙烯酸类化合物的官能化被优化，三氰乙基甘油可以作为树状聚合物的前手手性核心。

  DOI：

  10.1039/c5nj02223a

文献信息

• A film capacitor
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0319883A2

  公开（公告）日：1989-06-14

  The dielectric polymeric film in the inventive film capacitor is formed from a cyanoalkyl-containing organopolysiloxane repre­sented by the average unit formula R¹aR²bSiO(4-a-b)/2, in which R¹ ia a cyanoalkyl group having 3 to 5 carbon atoms, R² is a hydrogen atom, monovalent hydrocarbon group or halogenat­ed monovalent hydrocarbon group, the subscript a is a positive number in the range from 0.8 to 1.8 and the subscript b is zero or a positive number not exceeding 1.0 with the proviso that a + b is in the range from 1.1 to 1.98.

  本发明薄膜电容器中的介电聚合物薄膜是由一种含氰基烷基的有机聚硅氧烷形成的，其平均单元式为 R¹aR²bSiO(4-a-b)/2、 其中 R¹ ia 为具有 3 至 5 个碳原子的氰烷基，R² 为氢原子、一价烃基或卤代一价烃基，下标 a 为 0.8 至 1.8 范围内的正数，下标 b 为零或不超过 1.0 的正数，但 a + b 的范围为 1.1 至 1.98。
• Electroluminescent composition and electroluminescent device therewith
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0328120A2

  公开（公告）日：1989-08-16

  An electroluminescent device of the dispersion type exhibit­ing high brightness of electroluminescence and having excellent heat resistance and flexibility can be prepared by using, as the matrix material of the particulate electroluminescent mate­rial, a specific cyanoalkyl group-containing organopolysiloxane represented by the average unit formula R¹aR²bSiO(4-a-b)/2, in which R¹ is a cyanoalkyl group having 3 yo 5 carbon atoms, R² is a monovalent hydrocarbon group, a is 0.8 to 1.8 and b is 0 to 1.0 with the proviso that a+b is 1.1 to 1.98.

  作为微粒电致发光材料的基体材料，可以使用由平均单元式 R¹aR²bSiO(4-a-b)/2 表示的特定含氰基烷基有机聚硅氧烷来制备一种分散型电致发光装置，该装置具有高亮度的电致发光，并且具有优异的耐热性和柔韧性，其中 R¹ 是具有 3 至 5 个碳原子的氰基烷基，R² 是一价烃基，a 是 0.8 至 1.8，b 为 0 至 1.0，但 a+b 为 1.1 至 1.98。
• Highly dielectric addition type curable compositions
  申请人：——

  公开号：US20020198319A1

  公开（公告）日：2002-12-26

  A highly dielectric addition type curable composition is provided comprising (A) an organopolysiloxane containing a cyanoalkyl group and a monovalent hydrocarbon group having an aliphatic unsaturated bond, (B) an organohydrogenpolysiloxane containing a cyanoalkyl group, and (C) a platinum group metal catalyst. The composition is easy to handle because of liquid despite solvent-free, less hygroscopic and effectively curable, and has a film-forming ability. The cured composition has excellent dielectric properties as demonstrated by a large dielectric constant and a low dielectric loss.

  本发明提供了一种高介电加成型可固化组合物，该组合物由 (A) 含氰基烷基和具有脂肪族不饱和键的单价烃基的有机聚硅氧烷、(B) 含氰基烷基的有机氢聚硅氧烷和 (C) 铂族金属催化剂组成。该组合物尽管不含溶剂，但呈液态，易于处理，吸湿性较低，可有效固化，并具有成膜能力。固化后的组合物介电常数大、介电损耗低，具有极佳的介电性能。
• JPH02103895A
  申请人：——

  公开号：JPH02103895A

  公开（公告）日：1990-04-16
• LIGHT-EMITTING COMPOSITION, ELECTROLUMINESCENT SHEET, AND METHOD FOR PRODUCING SAME
  申请人：Naganawa Satoshi

  公开号：US20120242220A1

  公开（公告）日：2012-09-27

  A light-emitting composition comprising (A) a compound having a cyanoethyl group, (B) an adhesive resin material and (C) an electroluminescent material, wherein an amount of the component (B) is from 1 to 1,000 parts by mass per 100 parts by mass of the component (A); an electroluminescent sheet comprising at least a first electrode, an electroluminescent layer and a second electrode, laminated in this order, wherein at least one of the first electrode and the second electrode is transparent, and the electroluminescent layer contains the light-emitting composition; and a method for producing thereof are provided. Specifically, an electroluminescent sheet that can be produced at ambient temperature without heating, has high productivity, and can be mass produced at low cost, a method for producing thereof, and a light-emitting composition used therein are provided.