7,8-Dihydro-6H-pyrrolo<2.3-g>chinoxalin | 20771-32-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 7,8-Dihydro-6H-pyrrolo<2.3-g>chinoxalin
• 英文别名: 7,8-dihydro-6H-pyrrolo[2,3-g]quinoxaline；7,8-dihydro-6H-pyrrolo[2,3-g]quinoxaline
• CAS: 20771-32-8
• 化学式: C₁₀H₉N₃
• 分子量: 171.202
• InChiKey: FJTQNCVZTFZAOE-UHFFFAOYSA-N

物化性质

• 沸点：
  367.4±37.0 °C(Predicted)
• 密度：
  1.267±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  37.8
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Use Of Transition Metal Carbene Complexes In Organic Light-Emitting Diodes (Oleds)
  申请人：Egen Martina

  公开号：US20080018221A1

  公开（公告）日：2008-01-24

  The present invention relates to the use of transition metal-carbene complexes in organic light-emitting diodes (OLEDs), to a light-emitting layer, to a blocking layer for electrons or excitons, or to a blocking layer for holes, each comprising these transition metal-carbene complexes, to OLEDs comprising these transition metal-carbene complexes, to devices which comprise an inventive OLED, and to transition metal-carbene complexes.
• Method for the Isomerisation of Transition Metal Complexes Containing Cyclometallated, Carbene Ligands
  申请人：Molt Oliver

  公开号：US20080200686A1

  公开（公告）日：2008-08-21

  The present invention relates to a process for converting an isomerically pure compound C 1 of the formula I or a mixture M 1 comprising C 1 into an isomeric compound C 2 of the formula I which is different from C 1 or a mixture M 2 comprising C 2 , where the variables have the following meanings: n is 2 or 3; M is Pd or Pt, in each case in the formal oxidation state +II, when n is 2; and is Ru, Os, Co, Rh or Ir, in each case in the formal oxidation state +III, when n is 3; Do is a donor atom selected from the group consisting of N, O, S and P; r is 1 when Do is N or P, and is 0 when Do is O or S; Y 1 , Y 2 are each, independently of one another, hydrogen, alkyl, alkenyl, alkynyl, aryl, heteroaryl, alkyloxy, aryloxy, alkylthio, arylthio, alkylcarbonyl, arylcarbonyl, carboxyl, alkyloxycarbonyl, aryloxycarbonyl, hydroxysulfonyl, alkyloxysulfonyl, aryloxysulfonyl, halogen, CN, CHO, NO 2 or NO, or Y 1 and Y 2 together with the carbon atom to which they are bound form a six-membered aromatic ring which may comprise one or two nitrogen atoms and may optionally be fused with a further, optionally fused and optionally hetero-atom-comprising ring; Y 3 is alkyl, alkenyl, alkynyl, aryl or heteroaryl; A is a bridge having three or four atoms of which one or two atoms may be heteroatoms and the remaining atoms are carbon atoms, so that the group forms a five- or six-membered heteroaromatic ring or benzene ring which may optionally be substituted by substituents selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroaryl, alkyloxy, aryloxy, alkylthio, arylthio, alkylcarbonyl, arylcarbonyl, carboxyl, alkyloxycarbonyl, aryloxycarbonyl, hydroxysulfonyl, alkyloxysulfonyl, aryloxysulfonyl, halogen, CN, CHO, NO 2 and NO and may optionally be fused with a further, optionally heteroatom-comprising ring which may likewise be fused and substituted by substituents selected from the group consisting of alkyl, alkenyl, alkynyl, aryl, heteroaryl, alkyloxy, aryloxy, alkylthio, arylthio, alkylcarbonyl, arylcarbonyl, carboxyl, alkyloxycarbonyl, aryloxycarbonyl, hydroxysulfonyl, alkyloxysulfonyl, aryloxysulfonyl, halogen, CN, CHO, NO 2 and NO; which comprises allowing a Brönsted acid or a mixture of Brönsted acids to act on C 1 or M 1 in the presence of a solvent or solvent mixture at a temperature of from 0° C. to the boiling point of the solvent or the solvent mixture, with the proviso that a) the formation of C 2 from C 1 occurs under the conditions of the process and b) when both M 1 and M 2 are mixtures comprising C 1 and C2, the respective isomer ratios of C 1 and C 2 in the mixtures M 1 and M 2 are different from one another.
• USE OF TRANSITION METAL CARBENE COMPLEXES IN ORGANIC LIGHT-EMITTING DIODES (OLEDS)
  申请人：BASF SE

  公开号：US20140309428A1

  公开（公告）日：2014-10-16

  The present invention relates to the use of transition metal-carbene complexes in organic light-emitting diodes (OLEDs), to a light-emitting layer, to a blocking layer for electrons or excitons, or to a blocking layer for holes, each comprising these transition metal-carbene complexes, to OLEDs comprising these transition metal-carbene complexes, to devices which comprise an inventive OLED, and to transition metal-carbene complexes.
• US7803948B2
  申请人：——

  公开号：US7803948B2

  公开（公告）日：2010-09-28