catena-poly[triphenyltin-μ-(N,N-dimethylthiocarbamoylacetato-O:O')] | 7547-25-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: catena-poly[triphenyltin-μ-(N,N-dimethylthiocarbamoylacetato-O:O')]
• 英文别名: triphenyltin N,N-dimethylthiocarbamoylacetate
• CAS: 7547-25-3
• 化学式: C₂₃H₂₃NO₃SSn
• 分子量: 512.217
• InChiKey: WUTNPRQVSYMKLR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.06
• 重原子数：
  29.0
• 可旋转键数：
  6.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  38.77
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  <(Dimethylamino)(thiocarbonyl)oxy>essigsaeure 、 三苯基氢氧化锡 以 乙醇 为溶剂， 生成 catena-poly[triphenyltin-μ-(N,N-dimethylthiocarbamoylacetato-O:O')]
  参考文献：
  名称：

  TriphenyltinN,N-dimethylthiocarbamoylacetate, triphenyltinN,N-pentamethylenecarbamoylthioacetate and cyclopentyldiphenyltinN,N-dimethylthiocarbamoylacetate

  摘要：

  Carboxylate bridges link two independent molecules of triphenyltin N,N-dimethylthiocarbamoylacetate, [Sn(C6H5)(3)(C5H8NO3S)]. into a helical chain {i.e. catena-poly[triphenyltin-mu-(N,N-dimethylthiocarbamoylacetato-O:O')]}, as do the carboxylate bridges in triphenyltin N,N-pentamethylenecarbamoylthioacetate, [Sn(C6H5)(3)(C8H12NO3S)] {i.e. catena-poly[triphenyltin-mu-(N,N-pentamethylenethiocarbamoylacetato-O:O')]} and cyclo-pentyldiphenyltin N, N-dimethylthiocarbamoylacetate, [Sn(C6H5)(2)(C5H9)(C5H8NO3S)] {i.e. carena-poly[cyclo-pentyldiphenyltin-mu-(N,N-dimethylthiocarbomoylacetato-O:O')]}.

  DOI：

  10.1107/s0108270199001286