| 868529-01-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• CAS: 868529-01-5
• 化学式: C₃₀H₄₀P₂Pt
• 分子量: 657.675
• InChiKey: CWJHHNTZCVYMAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 二苯基乙炔 以 甲苯 为溶剂， 生成 {Pt(PhCCPh)(PEt3)2}
  参考文献：
  名称：

  Autocatalytic Alkyne Cycloadditions:  Evidence for Colloidal Pt Catalysis

  摘要：

  Treatment of the four-membered platinacycle L2Pt(1,8-naphthalendiyl) (1) or the five-membered platinacycle L2Pt(1,12-triphenylendiyl) with excess PhCCPh at 120-150 degrees C gives the coupling products 1,2-diphenylacenaphthalene or 4,5-diphenylbenzo[e]pyrene and the alkyne complex L2Pt(eta2-PhCCPh). Both reactions show an accelerating rate, which has been traced to catalysis of the reaction by colloidal platinum formed by the reaction of O2 with L2Pt(eta2-PhCCPh).

  DOI：

  10.1021/ja054863+
• 作为产物：
  描述：

  顺-二氯双(三乙基膦)铂(II) 、 1,12-dilithiotriphenylenediyl 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Autocatalytic Alkyne Cycloadditions:  Evidence for Colloidal Pt Catalysis

  摘要：

  Treatment of the four-membered platinacycle L2Pt(1,8-naphthalendiyl) (1) or the five-membered platinacycle L2Pt(1,12-triphenylendiyl) with excess PhCCPh at 120-150 degrees C gives the coupling products 1,2-diphenylacenaphthalene or 4,5-diphenylbenzo[e]pyrene and the alkyne complex L2Pt(eta2-PhCCPh). Both reactions show an accelerating rate, which has been traced to catalysis of the reaction by colloidal platinum formed by the reaction of O2 with L2Pt(eta2-PhCCPh).

  DOI：

  10.1021/ja054863+