5-hydroxy-4-methyl-hexanal cyclohemiacetal | 10413-11-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 英文名称: 5-hydroxy-4-methyl-hexanal cyclohemiacetal
• 英文别名: 5,6-dimethyl-tetrahydro-pyran-2-ol；5,6-Dimethyloxan-2-ol
• CAS: 10413-11-3
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: UZPFQKRAHNHBCV-UHFFFAOYSA-N

物化性质

• 沸点：
  84 °C(Press: 12 Torr)
• 密度：
  1.007 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-acetyl-4-cyano-2-methyl-butyric acid ethyl ester 在 钾硼氢 、 sodium carbonate 、 lithium chloride 作用下， 以 四氢呋喃 为溶剂， 生成 5-hydroxy-4-methyl-hexanal cyclohemiacetal
  参考文献：
  名称：

  Colonge,J. et al., Bulletin de la Societe Chimique de France, 1966, p. 2005 - 2011

  摘要：

  DOI：

文献信息

• Aziridine spinosyn derivatives and methods of making
  申请人：AgriMetis, LLC

  公开号：US10570165B2

  公开（公告）日：2020-02-25

  Compositions including derivatives of spinosyns and methods for the production of derivatives of spinosyns are provided. The spinosyn derivatives described herein include those functionalized on the C-5,6 double bond to provide an aziridine ring system. The method produces spinosyn derivatives that exhibit activity towards insects, arachnids, and nematodes and are useful in the agricultural and animal health markets.

  本研究提供了包括旋光花苷衍生物的组合物和生产旋光花苷衍生物的方法。本文所述的尖孢菌苷衍生物包括那些在 C-5,6 双键上官能化以提供氮丙啶环系统的衍生物。该方法生产出的尖孢菌苷衍生物对昆虫、蛛形纲动物和线虫具有活性，可用于农业和动物保健市场。
• ANTIREFLECTIVE COATING COMPOSITION, ANTIREFLECTIVE COATING, AND PATTERNING PROCESS
  申请人：Tachibana Seiichiro

  公开号：US20090087799A1

  公开（公告）日：2009-04-02

  A composition comprising (A) a polymer having an alcohol structure with plural fluorine atoms substituted at α- and α′-positions and having k=0.01-0.4 and (B) an aromatic ring-containing polymer having k=0.3-1.2 is used to form an antireflective coating. The ARC-forming composition can be deposited by the same process as prior art ARCs. The resulting ARC is effective in preventing reflection of exposure light in photolithography and has an acceptable dry etching rate.
• ANTIREFLECTIVE COATING COMPOSITION, ANTIREFLECTIVE COATING , AND PATTERNING PROCESS
  申请人：TACHIBANA Seiichiro

  公开号：US20100151381A1

  公开（公告）日：2010-06-17

  A composition comprising (A) a fluorinated polymer having k=0.01-0.4 and n=1.4-2.1 and (B) an aromatic ring-bearing polymer having k=0.3-1.2 is used to form an antireflective coating. The ARC-forming composition can be deposited by the same process as prior art ARCs. The resulting ARC is effective in preventing reflection of exposure light in photolithography and has an acceptable dry etching rate.
• AZIRIDINE SPINOSYN DERIVATIVES AND METHODS OF MAKING
  申请人：AgriMetis, LLC

  公开号：US20200148716A1

  公开（公告）日：2020-05-14

  Compositions including derivatives of spinosyns and methods for the production of derivatives of spinosyns are provided. The spinosyn derivatives described herein include those functionalized on the C-5,6 double bond to provide an aziridine ring system. The method produces spinosyn derivatives that exhibit activity towards insects, arachnids, and nematodes and are useful in the agricultural and animal health markets.
• US7879530B2
  申请人：——

  公开号：US7879530B2

  公开（公告）日：2011-02-01