1-(6-iodo-hexanoylmethyl)-4-vinyl-benzene | 1352171-29-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(6-iodo-hexanoylmethyl)-4-vinyl-benzene
• 英文别名: 6-(4-vinylbenzyloxy)-1-iodohexane；1-Ethenyl-4-(6-iodohexoxymethyl)benzene
• CAS: 1352171-29-9
• 化学式: C₁₅H₂₁IO
• 分子量: 344.236
• InChiKey: IBRQICUJAAVNKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(6-iodo-hexanoylmethyl)-4-vinyl-benzene 在 三甲基溴硅烷 、 对苯二酚 作用下， 以 二氯甲烷 为溶剂， 反应 22.0h， 生成 [6-(4-vinyl-benzyloxy)-hexyl]-phosphonic acid
  参考文献：
  名称：

  Structure and Properties of Polymer Electrolyte Membranes Containing Phosphonic Acids for Anhydrous Fuel Cells

  摘要：

  Recently, water-free, proton-conducting polymer electrolytes have been attracting attention because of their possible application as fuel cell membranes at intermediate temperatures (100 to 200 degrees C). Phosphonic acid groups are considered feasible anhydrous proton conducting moieties due to the high degree of proton self-dissociation arising from their intrinsic amphoteric character and high mobility of protonic charge carriers. In this work, we have synthesized and characterized model, phosphonic acidfunctionalized proton-conducting polymers, poly(vinylbenzyloxy-alkyl-phosphonic acid)s, for the purpose of exploring the relationship between molecular design, nanostructure, and performance characteristics. These novel proton conducting materials were characterized for their thermal stability, nanostructure, and performance properties. Thermogravimetric analysis (TGA) indicates that the polymers are thermally stable up to 140 degrees C, where the condensation of phosphonic acid groups starts to occur. Results from small-angle X-ray scattering (SAXS) show a peak corresponding to a Bragg spacing of approximately 21-24 angstrom, which is attributed to layerlike structure formation of the phosphonic acid containing conducting channels. The proton conductivity increases with temperature, reaching a value on the order of 3 X 10(-4) S/cm at 140 degrees C under nominally anhydrous conditions.

  DOI：

  10.1021/cm202064x
• 作为产物：
  描述：

  1,6-己二醇 在 sodium hydride 、 sodium iodide 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 、 丙酮 、 mineral oil 为溶剂， 反应 60.0h， 生成 1-(6-iodo-hexanoylmethyl)-4-vinyl-benzene
  参考文献：
  名称：

  Structure and Properties of Polymer Electrolyte Membranes Containing Phosphonic Acids for Anhydrous Fuel Cells

  摘要：

  Recently, water-free, proton-conducting polymer electrolytes have been attracting attention because of their possible application as fuel cell membranes at intermediate temperatures (100 to 200 degrees C). Phosphonic acid groups are considered feasible anhydrous proton conducting moieties due to the high degree of proton self-dissociation arising from their intrinsic amphoteric character and high mobility of protonic charge carriers. In this work, we have synthesized and characterized model, phosphonic acidfunctionalized proton-conducting polymers, poly(vinylbenzyloxy-alkyl-phosphonic acid)s, for the purpose of exploring the relationship between molecular design, nanostructure, and performance characteristics. These novel proton conducting materials were characterized for their thermal stability, nanostructure, and performance properties. Thermogravimetric analysis (TGA) indicates that the polymers are thermally stable up to 140 degrees C, where the condensation of phosphonic acid groups starts to occur. Results from small-angle X-ray scattering (SAXS) show a peak corresponding to a Bragg spacing of approximately 21-24 angstrom, which is attributed to layerlike structure formation of the phosphonic acid containing conducting channels. The proton conductivity increases with temperature, reaching a value on the order of 3 X 10(-4) S/cm at 140 degrees C under nominally anhydrous conditions.

  DOI：

  10.1021/cm202064x

文献信息

• A Polymer-Supported Chiral Fluorinated Dirhodium(II) Complex for Asymmetric Amination of Silyl Enol Ethers
  作者：Tadashi Oohara、Hisanori Nambu、Masahiro Anada、Koji Takeda、Shunichi Hashimoto

  DOI：10.1002/adsc.201200219

  日期：2012.8.13

  copolymerization of a dirhodium(II) complex-containing monomer with styrene and 1,6-bis(4-vinylbenzyloxy)hexane as a flexible cross-linker. The polymer-supported chiral fluorinated dirhodium(II) complex catalyzed the amination of silyl enol ethers with [N-(2-nitrophenylsulfonyl)imino]phenyliodinane (NsNIPh) to provide α-amino ketones in high yields with high levels of enantioselectivity and could be used

  四（N-四氟邻苯二甲酰基- （S）-叔亮氨酸酯] [Rh 2（S -TFPTTL）4 ]的四氢吡啶鎓（II）的固定化是通过将含二氢吡啶鎓（II）配合物的单体与苯乙烯共聚完成的。和1,6-双（4-乙烯基苄氧基）己烷作为柔性交联剂。聚合物负载的手性氟化二氢吡啶鎓（II）配合物催化甲硅烷基烯醇醚与[ N-（2-硝基苯基磺酰基）亚氨基]苯基碘丁烷（NsNIPh）的胺化反应，以高收率和高对映选择性提供α-氨基酮。在固体反应物的存在下，催化剂的使用量高达20倍，很容易经受住搅拌。