mer-[RuH(NO)(tris(3-sulfonatophenyl)phosphine)3](9-) | 732983-50-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: mer-[RuH(NO)(tris(3-sulfonatophenyl)phosphine)3](9-)
• 英文别名: mer-[RuH(NO)(TPPTS)3](9-)
• CAS: 732983-50-5
• 化学式: C₅₄H₃₇NO₂₈P₃RuS₉
• 分子量: 1630.46
• InChiKey: OAZDYOUGDCSHEK-UHFFFAOYSA-E

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuCl3(NO)(tris(3-sulfonatophenyl)phosphine)2](6-) 、 氢气 在 phosphate buffer 作用下， 以 further solvent(s) 为溶剂， 生成 mer-[RuH(NO)(tris(3-sulfonatophenyl)phosphine)3](9-)
  参考文献：
  名称：

  Water-soluble analogs of [RuCl3(NO)(PPh3)2] and their catalytic activity in the hydrogenation of carbon dioxide and bicarbonate in aqueous solution

  摘要：

  The new water-soluble ruthenium-nitrosyl complexes [RuCl3(NO)(TPPMS)(2)] and [RuCl3(NO)(TPPTS)(2)] were synthetized and characterized by IR, H-1 and P-31 NMR spectroscopies. The NO stretching frequencies, nu(NO) = 1870 cm(-1) (TPPMS) and 1883 cm(-1) (TPPTS) suggest a linear Ru-N-O arrangements. Reactions with OH- yield the corresponding [RuCl3 (NO2)(P)(2)] derivatives, furthermore, [RuH(NO)(P)(3)] is formed with TPPMS or TPPTS, respectively, under 100 bar H-2 pressure. The new complexes are suitable precatalysts for the hydrogenation of carbon dioxide and/or bicarbonate in aqueous solutions up to a turnover frequency of 400 h(-1) under relatively mild conditions (30 bar H-2, 70 degreesC). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(03)00293-0
• 作为试剂：
  描述：

  重碳酸钠-13C 、 二氧化碳 在 mer-[RuH(NO)(tris(3-sulfonatophenyl)phosphine)3](9-) 氢气 作用下， 以 水 、 重水 为溶剂， 生成 甲酸钠-13C
  参考文献：
  名称：

  Water-soluble analogs of [RuCl3(NO)(PPh3)2] and their catalytic activity in the hydrogenation of carbon dioxide and bicarbonate in aqueous solution

  摘要：

  The new water-soluble ruthenium-nitrosyl complexes [RuCl3(NO)(TPPMS)(2)] and [RuCl3(NO)(TPPTS)(2)] were synthetized and characterized by IR, H-1 and P-31 NMR spectroscopies. The NO stretching frequencies, nu(NO) = 1870 cm(-1) (TPPMS) and 1883 cm(-1) (TPPTS) suggest a linear Ru-N-O arrangements. Reactions with OH- yield the corresponding [RuCl3 (NO2)(P)(2)] derivatives, furthermore, [RuH(NO)(P)(3)] is formed with TPPMS or TPPTS, respectively, under 100 bar H-2 pressure. The new complexes are suitable precatalysts for the hydrogenation of carbon dioxide and/or bicarbonate in aqueous solutions up to a turnover frequency of 400 h(-1) under relatively mild conditions (30 bar H-2, 70 degreesC). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(03)00293-0