1-iodo-4,6,6,7,9,9,10,12,12,13,13,14,14,14-tetradecafluoro-4,7,10-tris(trifluoromethyl)-5,8,11-trioxatetradecane | 916597-58-5

• 分子结构分类: 有机化合物
• 英文名称: 1-iodo-4,6,6,7,9,9,10,12,12,13,13,14,14,14-tetradecafluoro-4,7,10-tris(trifluoromethyl)-5,8,11-trioxatetradecane
• 英文别名: 1,1,1,2-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]-5-iodopentane
• CAS: 916597-58-5
• 化学式: C₁₄H₆F₂₃IO₃
• 分子量: 786.068
• InChiKey: DPCVVVWZUJJDQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  41
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  正丙胺 、 1-iodo-4,6,6,7,9,9,10,12,12,13,13,14,14,14-tetradecafluoro-4,7,10-tris(trifluoromethyl)-5,8,11-trioxatetradecane 以 四氢呋喃 为溶剂， 反应 6.0h， 以92%的产率得到4,5,5,5-Tetrafluoro-4-{1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(heptafluoropropoxy)propoxy]propoxy}-N-propylpentan-1-amine
  参考文献：
  名称：

  WO2007/26513

  摘要：

  公开号：
• 作为产物：
  描述：

  2-(perfluoro-3,6,9-trioxa-5,8-dimethyldodeca-2-yl)propan-1-ol 在 磷酸 、 phosphorus pentoxide 、 potassium iodide 作用下， 反应 73.0h， 以95%的产率得到1-iodo-4,6,6,7,9,9,10,12,12,13,13,14,14,14-tetradecafluoro-4,7,10-tris(trifluoromethyl)-5,8,11-trioxatetradecane
  参考文献：
  名称：

  EP1886986

  摘要：

  公开号：

文献信息

• IODINE-CONTAINING FLUOROPOLYETHERS AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：Unimatec Co., Ltd.

  公开号：EP1886986A1

  公开（公告）日：2008-02-13

  An iodine-containing fluoropolyether represented by the following general formula [I]:         RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nI     [I] (where Rf is a perfluoroalkyl group having 1-3 carbon atoms, m is an integer of 0-10, and n is an integer of 3-12), is a novel compound having a perfluoropolyetheralkyl group capable of giving a flexibility to the molecule chain through the etheral bond, said perfluoropolyether alkyl group being bonded to the alkyl iodide having an alkyl group having 3 or more carbon atoms, and can be produced by reaction of a fluoropolyether group-containing alcohol represented by the following general formula [II]:         RfO[CF(CF3)CF2O]mCF(CF3)(CH2)nOH     [II] (Where Rf, m, avd n have the same meanings as defined above) with a metal iodide, preferably potassium iodide.

  由以下通式[I]表示的含碘含氟聚醚： RfO[CF(CF3)CF2O]mCF( )(CH2)nI [I]. (式中 Rf 为具有 1-3 个碳原子的全氟烷基，m 为 0-10 的整数，n 为 3-12 的整数)，是一种新型化合物，具有全氟聚醚烷基，能够通过醚键使分子链具有柔韧性，所述全氟聚醚烷基与具有 3 个或更多碳原子的烷基的碘化烷基键合，可通过由以下通式[II]表示的含氟聚醚基团的醇反应制得： RfO[CF( )CF2O]mCF( )( )nOH [II]. (其中 Rf、m、avd n 的含义与上述定义相同）与金属碘化物，最好是碘化钾。
• Iodine-containing fluoropolyether and process for producing the same
  申请人：Kokin Keisuke

  公开号：US20090048469A1

  公开（公告）日：2009-02-19

  An iodine-containing fluoropolyether represented by the following general formula [I]: RfO[CF(CF 3 )CF 2 O] m CF(CF 3 )(CH 2 ) n I  [I] (where Rf is a perfluoroalkyl group having 1-3 carbon atoms, m is an integer of 0-10, and n is an integer of 3-12), is a novel compound having a perfluoropolyetheralkyl group capable of giving a flexibility to the molecule chain through the etheral bond, said perfluoropolyether alkyl group being bonded to the alkyl iodide having an alkyl group having 3 or more carbon atoms, and can be produced by reaction of a fluoropolyether group-containing alcohol represented by the following general formula [II]: RfO[CF(CF 3 )CF 2 O] m CF(CF 3 )(CH 2 ) n OH  [II] (Where Rf, m, avd n have the same meanings as defined above) with a metal iodide, preferably potassium iodide.
• US7772443B2
  申请人：——

  公开号：US7772443B2

  公开（公告）日：2010-08-10