L-alanine acetate | 861107-90-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: L-alanine acetate
• 英文别名: LAlA；acetic acid;(2S)-2-aminopropanoic acid
• CAS: 861107-90-6
• 化学式: C₂H₄O₂*C₃H₇NO₂
• 分子量: 149.147
• InChiKey: HUMBVSRIRFYUFU-DKWTVANSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.49
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  101
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  L-alanine acetate 、 尿素 在 溶剂黄146 作用下， 以 水 为溶剂， 生成 urea L-alanine acetate adduct
  参考文献：
  名称：

  尿素-丙氨酸乙酸酯单晶的结构、光谱、热、介电、机械和光学性质

  摘要：

  摘要 一种新的有机非线性光学晶体, 尿素-丙氨酸乙酸酯 (ULAA) 通过溶液生长采用慢冷技术生长, 旨在改善 l-丙氨酸晶体的性能。尿素和 l-丙氨酸材料以 1:4 的摩尔比混合。测定溶解度和亚稳区宽度。单晶XRD分析表明，ULAA的晶格为正交晶系，原始晶格，晶胞参数a =5.7971 A，b =6.0391 A，c =12.3276 A，空间群为P2 1 2 1 2 1 (D 2 4 )。进行高分辨率 X 射线衍射 (HR-XRD) 分析以研究它们的结晶完整性。记录FTIR光谱以确定官能团的存在，并通过1 H NMR光谱确认分子结构。从质谱分析了ULAA的化合物形成比例。已使用热重 (TG) 和差热分析 (DTA) 研究了生长晶体的热强度。介电测量表明，生长的晶体具有非常低的介电损耗。通过维氏显微硬度试验研究了力学行为。发现生长的晶体在整个可见区域都是透明的。使用 Kurtz 粉末技术和波长为

  DOI：

  10.1016/j.physb.2010.02.053
• 作为产物：
  描述：

  L-丙氨酸 、 溶剂黄146 以 水 为溶剂， 生成 L-alanine acetate
  参考文献：
  名称：

  Influence of metal dopants (Cu and Mg) on the thermal, mechanical and optical properties of l-alanine acetate single crystals

  摘要：

  Single crystals of pure, Cu2+ and Mg2+ doped L-alanine acetate (LAlA) were grown successfully by slow evaporation technique. In the present study, to improve the device characteristics of LAlA crystals, metal dopants of Cu2+ and Mg2+ were incorporated into the pure crystals. The grown pure and doped LAlA crystals were confirmed by X-ray powder diffraction studies. The pure and doped crystals were characterized by Fourier Transform Infrared (FT-IR) and Thermal studies. Absorptions of the grown crystals were analyzed using UV-Vis-NIR studies which revealed that these crystals possess minimum absorption from 250 to 1800 nm. Further, it was found that the optical properties were enhanced by the incorporation of the dopants. Hardness, dielectric and photoconductivity studies were also carried out for the pure and doped LAlA crystals. Nonlinear optical studies of pure and doped crystals were carried out and it revealed that the dopant (Cu2+ and Mg2+) has increased the efficiency of the pure LAlA crystal. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.physb.2009.11.048

文献信息

• Influence of metal dopants (Cu and Mg) on the thermal, mechanical and optical properties of l-alanine acetate single crystals
  作者：D. Sankar、P. Praveen Kumar、J. Madhavan

  DOI：10.1016/j.physb.2009.11.048

  日期：2010.2

  Single crystals of pure, Cu2+ and Mg2+ doped L-alanine acetate (LAlA) were grown successfully by slow evaporation technique. In the present study, to improve the device characteristics of LAlA crystals, metal dopants of Cu2+ and Mg2+ were incorporated into the pure crystals. The grown pure and doped LAlA crystals were confirmed by X-ray powder diffraction studies. The pure and doped crystals were characterized by Fourier Transform Infrared (FT-IR) and Thermal studies. Absorptions of the grown crystals were analyzed using UV-Vis-NIR studies which revealed that these crystals possess minimum absorption from 250 to 1800 nm. Further, it was found that the optical properties were enhanced by the incorporation of the dopants. Hardness, dielectric and photoconductivity studies were also carried out for the pure and doped LAlA crystals. Nonlinear optical studies of pure and doped crystals were carried out and it revealed that the dopant (Cu2+ and Mg2+) has increased the efficiency of the pure LAlA crystal. (C) 2009 Elsevier B.V. All rights reserved.
• Structural, spectral, thermal, dielectric, mechanical and optical properties of urea l-alanine acetate single crystals
  作者：D. Jaikumar、S. Kalainathan、G. Bhagavannarayana

  DOI：10.1016/j.physb.2010.02.053

  日期：2010.5

  and differential thermal analysis (DTA). Dielectric measurements reveal that the grown crystals have very low dielectric loss. The mechanical behavior was studied by Vickers microhardness test. The grown crystals were found to be transparent in the entire visible region. Preliminary measurement using Kurtz powder technique with Nd-YAG laser light of wavelength 1064 nm indicates that their second harmonic

  摘要 一种新的有机非线性光学晶体, 尿素-丙氨酸乙酸酯 (ULAA) 通过溶液生长采用慢冷技术生长, 旨在改善 l-丙氨酸晶体的性能。尿素和 l-丙氨酸材料以 1:4 的摩尔比混合。测定溶解度和亚稳区宽度。单晶XRD分析表明，ULAA的晶格为正交晶系，原始晶格，晶胞参数a =5.7971 A，b =6.0391 A，c =12.3276 A，空间群为P2 1 2 1 2 1 (D 2 4 )。进行高分辨率 X 射线衍射 (HR-XRD) 分析以研究它们的结晶完整性。记录FTIR光谱以确定官能团的存在，并通过1 H NMR光谱确认分子结构。从质谱分析了ULAA的化合物形成比例。已使用热重 (TG) 和差热分析 (DTA) 研究了生长晶体的热强度。介电测量表明，生长的晶体具有非常低的介电损耗。通过维氏显微硬度试验研究了力学行为。发现生长的晶体在整个可见区域都是透明的。使用 Kurtz 粉末技术和波长为