1-(naphthalene-2-ylmethyl)-3,4-dihydronaphthalene-2(1H)-one | 263714-30-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 1-(naphthalene-2-ylmethyl)-3,4-dihydronaphthalene-2(1H)-one
• 英文别名: 1-(2-naphthylmethyl)-tetralone；1-(naphthalen-2-ylmethyl)-3,4-dihydro-1H-naphthalen-2-one
• CAS: 263714-30-3
• 化学式: C₂₁H₁₈O
• 分子量: 286.373
• InChiKey: JSMCHSWFLRWTDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(naphthalene-2-ylmethyl)-3,4-dihydronaphthalene-2(1H)-one 在 甲烷磺酸 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 生成 13H-dibenzo[a,g]fluorene
  参考文献：
  名称：

  A new general synthesis of polycyclic aromatic compounds based on enamine chemistry

  摘要：

  Alkylation of enamines and enamine salts by benzylic and (beta-haloethyl)aryl halides, respectively, followed by acidic cyclodehydration and dehydrogenation provides an efficient synthetic approach to a wide range of polycyclic aromatic compounds of diverse structural types. Specific polycyclic hydrocarbons synthesized by this route include benzo[a]- and benzo[c]fluorene, 7H-dibenzo[c,g]-, 13H-dibenzo[a,i]-, and 13H-dibenzo[a,g]fluorene, 15H-tribenzo[a,c,i]fluorene, dibenzo[b,def]chrysene, benzo[rst]pentaphene, indeno[1,2-b]fluorene, fluoreno[3,4-c]fluorene, octahydrodibenz[a,j]anthracene, dibenz[a,j]anthracene, octahydrodibenz[a,h]anthracene, dibenz[a,h]anthracene, dibenz[a,h]anthracene, picene, benzo[c]picene, 1H-benz[bc]aceanthrylene, and 4H-cyclopenta[def]chrysene. This method with appropriate modifications appears to be potentially broader in scope than established traditional methods of polycyclic hydrocarbon synthesis.

  DOI：

  10.1021/jo00003a050
• 作为产物：
  描述：

  β-四氢萘酮 在 对甲苯磺酸 作用下， 以 1,4-二氧六环 、 苯 为溶剂， 生成 1-(naphthalene-2-ylmethyl)-3,4-dihydronaphthalene-2(1H)-one
  参考文献：
  名称：

  A new general synthesis of polycyclic aromatic compounds based on enamine chemistry

  摘要：

  Alkylation of enamines and enamine salts by benzylic and (beta-haloethyl)aryl halides, respectively, followed by acidic cyclodehydration and dehydrogenation provides an efficient synthetic approach to a wide range of polycyclic aromatic compounds of diverse structural types. Specific polycyclic hydrocarbons synthesized by this route include benzo[a]- and benzo[c]fluorene, 7H-dibenzo[c,g]-, 13H-dibenzo[a,i]-, and 13H-dibenzo[a,g]fluorene, 15H-tribenzo[a,c,i]fluorene, dibenzo[b,def]chrysene, benzo[rst]pentaphene, indeno[1,2-b]fluorene, fluoreno[3,4-c]fluorene, octahydrodibenz[a,j]anthracene, dibenz[a,j]anthracene, octahydrodibenz[a,h]anthracene, dibenz[a,h]anthracene, dibenz[a,h]anthracene, picene, benzo[c]picene, 1H-benz[bc]aceanthrylene, and 4H-cyclopenta[def]chrysene. This method with appropriate modifications appears to be potentially broader in scope than established traditional methods of polycyclic hydrocarbon synthesis.

  DOI：

  10.1021/jo00003a050

文献信息

• AMINODIBENZOFLUORENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：TAKASHIMA Yoriyuki

  公开号：US20090267491A1

  公开（公告）日：2009-10-29

  A novel compound which is useful as a constitutional component for an organic EL device is provided by an aminodibenzofluorene derivative comprising (A) at least one dibenzofluorene structure and (B) at least one amino group in a molecule, a material for an organic electroluminescence (EL) device comprising the same, a light emitting material for an organic EL device, a light emitting organic solution, an organic EL device in which an organic compound layer comprising a single layer or plural layers including at least a light emitting layer is interposed between a pair of electrodes, wherein at leas one layer in the organic compound layer described above contains at least one kind of the aminodibenzofluorene derivative described above and an equipment comprising the same. A practical organic EL device which has a low operating voltage, a long lifetime and a high current efficiency and which provides blue light emission having an excellent color purity is materialized by using the above compound.

  提供了一种新型化合物，可作为有机EL器件的构成组分，该化合物由包含（A）至少一个二苯并芴结构和（B）至少一个氨基团的氨基二苯并芴衍生物组成，一种用于有机电致发光（EL）器件的材料，一种用于有机EL器件的发光材料，一种发光有机溶液，一种有机EL器件，其中在一对电极之间夹设了包括至少一个发光层的单层或多层的有机化合物层，上述有机化合物层中的至少一层含有上述氨基二苯并芴衍生物中的至少一种，以及包括该化合物的设备。通过使用上述化合物，可以实现具有低工作电压、长寿命和高电流效率的实用有机EL器件，并提供具有优异色纯度的蓝光发射。
• Aminodibenzofluorene derivative and organic electroluminescence device using the same
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：US07838130B2

  公开（公告）日：2010-11-23

  A novel compound which is useful as a constitutional component for an organic EL device is provided by an aminodibenzofluorene derivative comprising (A) at least one dibenzofluorene structure and (B) at least one amino group in a molecule, a material for an organic electroluminescence (EL) device comprising the same, a light emitting material for an organic EL device, a light emitting organic solution, an organic EL device in which an organic compound layer comprising a single layer or plural layers including at least a light emitting layer is interposed between a pair of electrodes, wherein at leas one layer in the organic compound layer described above contains at least one kind of the aminodibenzofluorene derivative described above and an equipment comprising the same. A practical organic EL device which has a low operating voltage, a long lifetime and a high current efficiency and which provides blue light emission having an excellent color purity is materialized by using the above compound.

  本发明提供了一种新型化合物，其作为有机EL器件的组成部分非常有用，该化合物是由氨基二苯并芴衍生物组成，包括（A）至少一个二苯并芴结构和（B）至少一个氨基团在一个分子中。还提供了一种用于有机电致发光（EL）器件的材料，一种用于有机EL器件的发光材料，一种发光有机溶液，一种有机化合物层中包括至少一个发光层的单层或多层，该有机化合物层被夹在一对电极之间的有机EL器件，其中上述有机化合物层中的至少一层包含上述氨基二苯并芴衍生物的至少一种，并提供了一种包括该化合物的设备。通过使用上述化合物，实现了一种实用的有机EL器件，该器件具有低操作电压、长寿命和高电流效率，并提供具有优异色纯度的蓝光发射。
• N-ARALKYLAMINOTETRALINS AS LIGANDS FOR THE NEUROPEPTIDE Y Y5 RECEPTOR
  申请人：Ortho-McNeil Pharmaceutical, Inc.

  公开号：EP1119543B1

  公开（公告）日：2004-12-15
• US6201025B1
  申请人：——

  公开号：US6201025B1

  公开（公告）日：2001-03-13
• US7838130B2
  申请人：——

  公开号：US7838130B2

  公开（公告）日：2010-11-23