[2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphyrinato]zinc*THF | 347144-87-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphyrinato]zinc*THF
• CAS: 347144-87-0
• 化学式: C₄₈H₂₈F₈N₄OZn
• 分子量: 894.154
• InChiKey: WFVZRKIOTQBBBV-KXMZQQCASA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氢呋喃 、 Zn(II)(2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphyrin) 以 四氢呋喃 、 正辛烷 为溶剂， 生成 [2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetraphenylporphyrinato]zinc*THF
  参考文献：
  名称：

  Structure and Photophysics of β-Octafluoro-meso-tetraarylporphyrins

  摘要：

  The structure of THF-coordinated [2,3,7,8,12,13,17, 18-octafluoro-5,10, 15,20-tetraphenylporphinato]zinc, Zn(F-8-TPP) THF, and photophysical studies of 2,3,7,8,12,13, 17,18-octafluoro-5, 10, 15,20-tetraphenylporphyrin, F8TPP, Zn(F8TPP), 2,3,7,8,12,13,17,18-octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin F28TPP, and [2,3,7,8, 12,13,17,18-octafluoro-5,10, 15,20-tetrakis(pentafluorophenyl)porphinato]zinc Zn(F28TPP), in benzonitrile, are reported. A key point from these studies is that the octafluorinated F8TPP and perfluorinated F28TPP porphyrins possess similar absorption spectra, but dissimilar X-ray crystal structures and disparate photophysical characteristics. These data cannot be easily accommodated within currently accepted theories which relate macrocycle distortion and optoelectronic properties.

  DOI：

  10.1021/ic001116z