[[[3-[bis(triethylphosphine)][[3-[iodide-[bis(triethylphosphine)]platinum]ethynyl]-[5-(pyren-1-ylethynyl)phenyl]ethynyl]platinumethynyl]-[5-(pyren-1-ylethynyl)]phenyl]ethynyl][[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl]-platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynyl]bis(triethylphosphine)platinum | 1430799-55-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: [[[3-[bis(triethylphosphine)][[3-[iodide-[bis(triethylphosphine)]platinum]ethynyl]-[5-(pyren-1-ylethynyl)phenyl]ethynyl]platinumethynyl]-[5-(pyren-1-ylethynyl)]phenyl]ethynyl][[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl]-platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynyl]bis(triethylphosphine)platinum
• CAS: 1430799-55-5
• 化学式: C₁₅₈H₁₆₉IP₈Pt₄
• 分子量: 3223.09
• InChiKey: ALLXUKZFAOPSFH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trans diiodobis(triethylphosphine)platinum(II) 、 [[[3-[bis(triethylphosphine)][[3-ethynyl-5-(pyren-1-ylethynyl)phenyl]ethynyl]platinumethynyl][5-(pyren-1-ylethynyl)]phenyl]ethynyl][[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl]platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynyl]bis(triethylphosphine)platinum 在 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以70%的产率得到[[[3-[bis(triethylphosphine)][[3-[iodide-[bis(triethylphosphine)]platinum]ethynyl]-[5-(pyren-1-ylethynyl)phenyl]ethynyl]platinumethynyl]-[5-(pyren-1-ylethynyl)]phenyl]ethynyl][[[3-[[bis(triethylphosphine)][3-(pyren-1-ylethynyl)phenylethynyl]-platinumethynyl]][5-(pyren-1-ylethynyl)]phenyl]ethynyl]bis(triethylphosphine)platinum
  参考文献：
  名称：

  Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

  摘要：

  A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C-H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (H-1, C-13, and P-31) and mass spectrometry (MALDI-TOF-MS). Preliminary spectroscopic studies of these oligomers were also carried out.

  DOI：

  10.1007/s00706-012-0892-4