cis-bis(acetato)bis(2-methylimidazole)copper(II) | 140925-84-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: cis-bis(acetato)bis(2-methylimidazole)copper(II)
• 英文别名: copper;2-methyl-1H-imidazole;diacetate
• CAS: 140925-84-4；103822-50-0
• 化学式: C₁₂H₁₈CuN₄O₄
• 分子量: 345.845
• InChiKey: OKXFNXAFJISPRM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基咪唑 、 copper diacetate 以 甲醇 、 氯仿 为溶剂， 生成 cis-bis(acetato)bis(2-methylimidazole)copper(II)
  参考文献：
  名称：

  Synthesis and molecular structure of monomeric copper(II) acetates with 2-methylimidazole and 1,2-dimethylimidazole

  摘要：

  The complexes cis-bis(acetato)bis(2-methylimidazole)copper(II) (1), and cis-bis(acetato)bis(1,2-dimethylimidazole)copper(II) (2) have been prepared by the reaction of the appropriate imidazole derivative with copper(II) tetraacetate. The complexes have been characterized by analytical, magnetic, spectroscopic and crystallographic methods. Complex 1 crystallizes in the orthorhombic space group P2(1)2(1)2(1) and has unit cell dimensions of a = 7.5380(10), b = 7.7100(10), c = 26.310(5) angstrom. Complex 2 crystallizes in the monoclinic space group P2/c and has unit cell dimensions of a = 15.574(2), b = 7.9520(10), c = 14.752(2) angstrom.

  DOI：

  10.1016/s0020-1693(00)80226-1