(3-phenoxyphenyl)methyl 3-[(Z)-2-chloro-3,3,3-trifluoro-prop-1-enyl]-2,2-dimethyl-cyclopropanecarboxylate | 68086-49-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (3-phenoxyphenyl)methyl 3-[(Z)-2-chloro-3,3,3-trifluoro-prop-1-enyl]-2,2-dimethyl-cyclopropanecarboxylate
• 英文别名: (3-phenoxyphenyl)methyl 3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropanecarboxylate；(3-phenoxyphenyl)methyl 2,2-dimethyl-3-(2-chloro-3,3,3-trifluoro-1-propenyl)cyclopropanecarboxylate；3-phenoxybenzyl trans-3-[2-chloro-3,3,3-trifluoropropenyl]-2,2-dimethylcyclopropanecarboxylate；3'-phenoxybenzyl 2,2-dimethyl-3-(2-chloro-2-trifluoromethylvinyl)cyclopropanecarboxylate；3-(2-Chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid 3-phenoxybenzyl ester；(3-phenoxyphenyl)methyl 3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate
• CAS: 68086-49-7；68127-78-6；68127-79-7；68127-80-0；71698-60-7；72748-55-1；72748-56-2；73176-68-8；74111-96-9；74111-97-0；100937-95-9；107794-42-3；110508-49-1；111902-15-9
• 化学式: C₂₂H₂₀ClF₃O₃
• 分子量: 424.847
• InChiKey: RTRBHVOKZNZJDH-PDGQHHTCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  29
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-phenoxyphenylmethyl 2,2-dimethyl-3-(1-hydroxy-2,2-dichloro-3,3,3-trifluoropropyl)cyclopropanecarboxylate 生成 (3-phenoxyphenyl)methyl 3-[(Z)-2-chloro-3,3,3-trifluoro-prop-1-enyl]-2,2-dimethyl-cyclopropanecarboxylate
  参考文献：
  名称：

  XIYAMA, TAMEHDZIRO;FUDZITA, MAKOTO

  摘要：

  DOI：

文献信息

• [EN] AGRICULTURAL CHEMICALS<br/>[FR] PRODUITS CHIMIQUES AGRICOLES
  申请人：REDX PHARMA LTD

  公开号：WO2013136073A1

  公开（公告）日：2013-09-19

  The present invention relates to derivatives of compounds which are known to be of use in the field of agriculture. These derivatives are differentiated from the parent active compound by virtue of being redox derivatives of the active compound. This means that one or more of the functional groups in the active compound has been converted to another group in one or more changes one or more of which may be considered to represent a change of oxidation state relative to the groups in the original compound. We refer to these compounds generally as redox derivatives. The compounds are of use as insecticides, herbicides and insect repellents.

  本发明涉及与已知在农业领域中有用的化合物衍生物。这些衍生物通过成为活性化合物的氧化还原衍生物而与母体活性化合物区分开来。这意味着活性化合物中的一个或多个官能团已被转化为另一个官能团，其中一个或多个变化可能被认为代表相对于原始化合物中的官能团的氧化状态的变化。我们通称这些化合物为氧化还原衍生物。这些化合物可用作杀虫剂、除草剂和驱虫剂。
• AGRICULTURAL CHEMICALS
  申请人：Redx Pharma Ltd.

  公开号：US20150094474A1

  公开（公告）日：2015-04-02

  The present invention relates to derivatives of compounds which are known to be of use in the field of agriculture. These derivatives are differentiated from the parent active compound by virtue of being redox derivatives of the active compound. This means that one or more of the functional groups in the active compound has been converted to another group in one or more changes one or more of which may be considered to represent a change of oxidation state relative to the groups in the original compound. We refer to these compounds generally as redox derivatives. The compounds are of use as insecticides, herbicides and insect repellents.

  本发明涉及与农业领域中已知有用的化合物衍生物。这些衍生物通过成为活性化合物的氧化还原衍生物而与母体活性化合物区分开来。这意味着活性化合物中的一个或多个官能团已经转化为另一个官能团，其中一个或多个转变可能被认为代表相对于原始化合物中的官能团的氧化状态的变化。我们通常将这些化合物称为氧化还原衍生物。这些化合物可用作杀虫剂、除草剂和驱虫剂。
• Fluoralkenylsubstituierte Cyclopropancarbonsäureester, Zwischenprodukte dafür, Herstellung der Verbindungen und ihre Verwendung als Insektizide und/oder Akarizide
  申请人：BAYER AG

  公开号：EP0008340A1

  公开（公告）日：1980-03-05

  Die vortiegende Erfindung betrifft neue fluonlkenylsubstituierte Cyclopropancarbonsäureester der Formel in welcher R1, R2, R2 die in der Beschreibung angegebene Bedeutung haben sowie Verfahren zu ihrer Herstellung und Zwischenprodukte dazu.

  本发明涉及新的氟烯基取代环丙烷羧酸酯，其式为 其中 R1、R2、R2 具有描述中给出的含义，以及其制备工艺和中间体。
• 2,2-Dimethylcyclopropanecarboxylic acid derivatives
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0217342A1

  公开（公告）日：1987-04-08

  A 2.2-dimethylcyclopropanecarboxylic acid derivative having the formula: wherein R1 is an alkyl group or an aryl group, R2 is a hydrogen atom, an acyl group, a sulfonyl group or an alkyl group, and each of X1 and X2 is a halogen atom.

  一种 2.2-二甲基环丙烷羧酸衍生物，其式如下 其中 R1 为烷基或芳基，R2 为氢原子、酰基、磺酰基或烷基，X1 和 X2 各为卤素原子。
• Insecticidal resin coating film
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0257415A1

  公开（公告）日：1988-03-02

  An insecticidal resin coating film comprising a combination of an acrylonitrile and/or methacrylonitrile copolymer resin and an insecticidal component selected from the group consisting of specified compounds exhibits an insecticidal effect, since the compound is kept on the surface of the coating film in a state capable of exhibiting its insecticidal effect for a long period of time.

  杀虫树脂涂膜由丙烯腈和/或甲基丙烯腈共聚物树脂和从特定化合物组成的组中选出的杀虫成分组合而成，具有杀虫效果，因为化合物在涂膜表面保持的状态能够长时间显示其杀虫效果。