2,3-dimethoxy-7,14-di-tert-butyltriptycene | 1571858-98-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3-dimethoxy-7,14-di-tert-butyltriptycene
• CAS: 1571858-98-4
• 化学式: C₃₀H₃₄O₂
• 分子量: 426.599
• InChiKey: DWBWPLHNDVYNMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.29
• 重原子数：
  32.0
• 可旋转键数：
  2.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  2,3-dimethoxy-7,14-di-tert-butyltriptycene 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 以85%的产率得到2,3-dihydroxy-7,14-di-tert-butyltriptycene
  参考文献：
  名称：

  Triptycene-Based Organic Molecules of Intrinsic Microporosity

  摘要：

  Four Organic Molecules of Intrinsic Microporosity (OMIMs) were prepared by fusing triptycene-based components to a biphenyl core. Due to their rigid molecular structures that cannot pack space efficiently, these OMIMs form amorphous materials with significant microporosity as demonstrated by apparent BET surface areas in the range of 515-702 m(2) g(-1). Bulky cyclic 1',2',3',4'-tetrahydro-1',1',4',4'-tetramethylbenzo units placed on the triptycene termini are especially efficient at enhancing microporosity.

  DOI：

  10.1021/ol500591q
• 作为产物：
  描述：

  2,6-二-叔丁基蒽 、 4,5-dimethoxybenzenediazonium-2-carboxylate chloride 在 methyloxirane 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 24.0h， 以16%的产率得到2,3-dimethoxy-7,14-di-tert-butyltriptycene
  参考文献：
  名称：

  Triptycene-Based Organic Molecules of Intrinsic Microporosity

  摘要：

  Four Organic Molecules of Intrinsic Microporosity (OMIMs) were prepared by fusing triptycene-based components to a biphenyl core. Due to their rigid molecular structures that cannot pack space efficiently, these OMIMs form amorphous materials with significant microporosity as demonstrated by apparent BET surface areas in the range of 515-702 m(2) g(-1). Bulky cyclic 1',2',3',4'-tetrahydro-1',1',4',4'-tetramethylbenzo units placed on the triptycene termini are especially efficient at enhancing microporosity.

  DOI：

  10.1021/ol500591q