| 864066-75-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 864066-75-1
• 化学式: C₁₄₄H₁₈₄N₂₂O₈S₁₆
• 分子量: 2864.24
• InChiKey: VBNMMGWZOXSNDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.56
• 重原子数：
  190.0
• 可旋转键数：
  93.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  442.56
• 氢给体数：
  8.0
• 氢受体数：
  38.0

反应信息

• 作为产物：
  描述：

  4-氰基-4-[（苯基硫代甲基）硫代]-2,5-二氧代-1-吡咯烷基酯戊酸 、 4,17-二(3-氨基丙基)-8,13-二(3-(二(3-氨基丙基)氨基)丙基)-4,8,13,17-四氮杂二十烷-1,20-二胺 以 二氯甲烷 为溶剂， 反应 48.0h， 以95%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Dendrimer-Star Polymer Using Dithiobenzoate-Terminated Poly(propylene imine) Dendrimer via Reversible Addition-Fragmentation Transfer Polymerization

  摘要：

  Two new reversible addition-fragmentation transfer (RAFT) agents with 8 and 16 terminal dithiobenzoate groups on the surface of poly(propylene imine) dendrimers (generation 2.0 and 3.0, respectively) were prepared, and successively they were used in the RAFT polymerization to produce well-defined dendrimer-star polymers. The polymerization kinetics were confirmed to pseudo-first-order behavior. The polymerizations displayed excellent molecular weight control and produced polymer with low polydispersities (< 1.3). The synthetic method was also suitable for the preparation of dendrimerstar block copolymers.

  DOI：

  10.1021/ma050455e