[N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Ni] | 304852-80-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Ni]
• 英文别名: [N,N'-Phenylen-bis(3-formyl-5-tert.-butyl-salicylaldimin)Ni]
• CAS: 304852-80-0
• 化学式: C₃₀H₃₀N₂NiO₄
• 分子量: 541.269
• InChiKey: QBNYYCPNARHNMT-KFZCUDJASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Ni] 、 cobalt(II) perchlorate hexahydrate 、 1,3-丙二胺 以 乙醇 为溶剂， 以36%的产率得到
  参考文献：
  名称：

  摘要：

  The synthesis and properties of nickel(II), copper(II), and palladium(II) complexes, [MLPh] (3; L-Ph = N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)), are described. These neutral mononuclear complexes react with metal(II) perchlorate and 1,3-propylenediamine to form heterodinuclear, macrocyclic, cationic complexes of the type [MM'(L-Ph,L-3)](2+) (4; M = Ni, Cu, Pd; M' = Co, Cu, Zn). The structures of the five new compounds [NiCo(L-Ph,L-3)](ClO4)(2), [NiCu(L-Ph,L-3)](ClO4)(2), [CuCu(L-Ph,L-3)](ClO4)(2), [CuZn(L-Ph,L-3)](ClO4)(2), and [PdCu(L-Ph,L-3)](ClO4)(2) were determined by X-ray diffraction.

  DOI：

  10.1002/1521-3749(200009)626:9<1934::aid-zaac1934>3.0.co;2-g
• 作为产物：
  描述：

  4-叔丁基-2,6-二甲酰基苯酚 、 nickel diacetate 、 间苯二胺 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 以40%的产率得到[N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)Ni]
  参考文献：
  名称：

  摘要：

  The synthesis and properties of nickel(II), copper(II), and palladium(II) complexes, [MLPh] (3; L-Ph = N,N'-phenylene-bis(3-formyl-5-tert.-butyl-salicylaldimine)), are described. These neutral mononuclear complexes react with metal(II) perchlorate and 1,3-propylenediamine to form heterodinuclear, macrocyclic, cationic complexes of the type [MM'(L-Ph,L-3)](2+) (4; M = Ni, Cu, Pd; M' = Co, Cu, Zn). The structures of the five new compounds [NiCo(L-Ph,L-3)](ClO4)(2), [NiCu(L-Ph,L-3)](ClO4)(2), [CuCu(L-Ph,L-3)](ClO4)(2), [CuZn(L-Ph,L-3)](ClO4)(2), and [PdCu(L-Ph,L-3)](ClO4)(2) were determined by X-ray diffraction.

  DOI：

  10.1002/1521-3749(200009)626:9<1934::aid-zaac1934>3.0.co;2-g