[Co(3,3',4,4',5,5'-hexamethyl-2,2'-dipyrrolylmethene(-H))2] | 21710-27-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Co(3,3',4,4',5,5'-hexamethyl-2,2'-dipyrrolylmethene(-H))2]
• 英文别名: cobalt(2+);(5Z)-2,3,4-trimethyl-5-[(3,4,5-trimethylpyrrol-1-id-2-yl)methylidene]pyrrole
• CAS: 21710-27-0
• 化学式: C₃₀H₃₈CoN₄
• 分子量: 513.652
• InChiKey: KBTVUDVQTAWFRK-CQNCLULFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) diacetate tetrahydrate 、 2,3,4-Trimethyl-5-[(3,4,5-trimethyl-2H-pyrrol-2-ylidene)methyl]-1H-pyrrole hydrobromide (1:1) 以 N,N-二甲基甲酰胺 为溶剂， 生成 [Co(3,3',4,4',5,5'-hexamethyl-2,2'-dipyrrolylmethene(-H))2]
  参考文献：
  名称：

  Dipyrromethene as multifunctional sensor towards d-metal cations

  摘要：

  DOI：

  10.1016/j.jphotochem.2024.115687

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: SVol.B1, 24, page 50 - 53
  作者：

  DOI：——

  日期：——
• Johnson, A. W.; Kay, J. T.; Markham, E., Journal of the Chemical Society
  作者：Johnson, A. W.、Kay, J. T.、Markham, E.、Price, R.、Shaw, K. B.

  DOI：——

  日期：——
• Complex formation of Cu(II), Ni(II), Zn(II), Co(II), and Cd(II) acetates with 3,3′,4,4′,5,5′-hexamethyldipyrrolylmethene
  作者：G. B. Guseva、E. V. Antina、A. I. V’yugin、A. E. Loginova

  DOI：10.1134/s1070328408080071

  日期：2008.8

  The reactions of complex formation of Cu(II), Co(II), Zn(II), Ni(II), and Cd(II) acetates with 3,3',4,4'5,5'-hexamethyl-2,2'-dipyrrolylmethene (HL) in DMF were studied by the electronic spectroscopy and calorimetric titration methods at 298.15 K. The main products of the above reactions are [ML2] chelates. In the case of Cu and Ni salts, the process occurs through the spectrally recorded stage of formation of the heteroligand [ML(AcO)] complexes. The reaction with Cd acetate terminates at the stage of the heteroligand complex formation due to the large radius and decreasing electron affinity of the Cd2+ ion. The effect of the metal nature appears in the increasing thermodynamic stability of single-type complexes in the series [ML2]: Ni(II) < Zn(II) < Co(II) < Cu(II) and [ML(AcO)]: Cd(II) < Ni(II) < Cu(II).