[Cu(8-quinolinecarboxaldehyde thiosemicarbazone(-1H))(NO3)] | 1293919-18-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Cu(8-quinolinecarboxaldehyde thiosemicarbazone(-1H))(NO3)]
• CAS: 1293919-18-2
• 化学式: C₂₂H₁₈Cu₂N₁₀O₆S₂
• 分子量: 709.672
• InChiKey: JNONTXDQMKNDLR-SOBWDFFCSA-L

反应信息

• 作为产物：
  描述：

  [Cu(8-quinolinecarboxaldehyde thiosemicarbazone)(NO3)2]*2H2O 在 NH₄NO₃ 作用下， 以 水 为溶剂， 生成 [Cu(8-quinolinecarboxaldehyde thiosemicarbazone(-1H))(NO3)]
  参考文献：
  名称：

  Synthesis and structure of copper(II) coordination compounds with 8-quinolinecarboxaldehyde thio- and 4-phenylthiosemicarbazones

  摘要：

  8-Quinolinecarboxaldehyde thiosemicarbazone (HL) and copper form compounds with a metal : ligand ratio of 1 : 1 in which the ligand is either the neutral molecule or the monohydric acid anion. Its acidic properties are enhanced not only as a result of coordination but also due to the electronic effect of substituents in the thiosemicarbazide moiety. 8-Quinolinecarboxaldehyde 4-phenylthiosemicarbazone (HL1) is coordinated only as the anion. The structures of [Cu(HL)SO4](2), [Cu(L)NO3](2), and [Cu(L-1)NO3](2) center dot 0.25H(2)O, and free HL1 were studied. The tendency of the complexes to dimerization and association with acid anions or sulfur atoms of the organic ligands as bridges was established. In binuclear compounds with closely spaced magnetic centers, no exchange interaction between them was found. The copper coordination compounds with HL are able to suppress the growth of cancer cells 41M and SK-BR-3 and are promising objects for investigation as anticancer drugs.

  DOI：

  10.1134/s0036023610090093