7-dodecyl-5H-dinaphtho[2,3-b:2',3'-h]carbazole-5,9,14,17(7H)-tetraone | 1404191-38-3

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 7-dodecyl-5H-dinaphtho[2,3-b:2',3'-h]carbazole-5,9,14,17(7H)-tetraone
• CAS: 1404191-38-3
• 化学式: C₄₀H₃₇NO₄
• 分子量: 595.738
• InChiKey: XUHPYQKWLVSXQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.64
• 重原子数：
  45.0
• 可旋转键数：
  11.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  73.21
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  7-dodecyl-5H-dinaphtho[2,3-b:2',3'-h]carbazole-5,9,14,17(7H)-tetraone 在 四溴化碳 、 氢化铝 、 mercury dichloride 作用下， 以 环己醇 为溶剂， 反应 3.0h， 以78%的产率得到7-dodecyl-7H-dinaphtho[2,3-b:2',3'-h]carbazole
  参考文献：
  名称：

  N-Alkyldinaphthocarbazoles, Azaheptacenes, for Solution-Processed Organic Field-Effect Transistors

  摘要：

  Substituted N-alkyldinaphthocarbazoles were synthesized using a key double Diets-Alder reaction. The angular nature of the dinaphthocarbazole system allows for increased stability of the conjugated system relative to linear analogues. The N-alkyldinaphthocarbazoles were characterized by UV-vis absorption and fluorescence spectroscopy as well as cyclic voltammetry. X-ray structure analysis based on synchrotron X-ray powder diffraction revealed that the N-dodecyl-substituted compound was oriented in an intimate herringbone packing motif, which allowed for p-type mobilities of 0.055 cm(2) V-1 s(-1) from solution-processed organic field-effect transistors.

  DOI：

  10.1021/ja3082582