| 1246291-67-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• CAS: 1246291-67-7
• 化学式: C₂₄H₃₃ClN₂O₄
• 分子量: 448.99
• InChiKey: IMNANFLGNMGHDJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.88
• 重原子数：
  31.0
• 可旋转键数：
  14.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  81.16
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  、 phenyldithiocarboxylic acid magnesium bromide 以 四氢呋喃 为溶剂， 反应 24.0h， 以52%的产率得到
  参考文献：
  名称：

  Heterocomplementary H-Bonding RAFT Agents as Tools for the Preparation of Supramolecular Miktoarm Star Copolymers

  摘要：

  Supramolecular miktoarm stars (AB(2) type) composed of poly (methyl methacrylate)-polystyrene(2) (PM MA-PS. poly(isoprene)-polystyrene2 (PI-PS2), and poly(vinyl acetate)-polystyrene, (PVAc-PS2) were successfully synthesized by assembling reversible addition fragmentation chain transfer (RA FT)-polymerized chains bearing hydrogen-bonding heterocomplementary associating units To this end, thymine and diaminopyridine-Functionalized chain transfer agents were designed to efficiently mediate the polymerization of vinyl acetate, methyl methacrylate. isoprene, and styrene The selective associations of the resulting hydrogen-bonding macromolecular building blocks PVAc/PS. PI/PS, and PMMA/PS were demonstrated by H-1 NMR in CDCl3 solutions Miktoarm stars formation in the bulk was also confirmed by transmission electronic microscopy

  DOI：

  10.1021/ma101044y
• 作为产物：
  描述：

  1-(11-hydroxyundecyl)thymine 、 DL-2-氯-2-苯基乙酰氯 在 吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以80%的产率得到
  参考文献：
  名称：

  Heterocomplementary H-Bonding RAFT Agents as Tools for the Preparation of Supramolecular Miktoarm Star Copolymers

  摘要：

  Supramolecular miktoarm stars (AB(2) type) composed of poly (methyl methacrylate)-polystyrene(2) (PM MA-PS. poly(isoprene)-polystyrene2 (PI-PS2), and poly(vinyl acetate)-polystyrene, (PVAc-PS2) were successfully synthesized by assembling reversible addition fragmentation chain transfer (RA FT)-polymerized chains bearing hydrogen-bonding heterocomplementary associating units To this end, thymine and diaminopyridine-Functionalized chain transfer agents were designed to efficiently mediate the polymerization of vinyl acetate, methyl methacrylate. isoprene, and styrene The selective associations of the resulting hydrogen-bonding macromolecular building blocks PVAc/PS. PI/PS, and PMMA/PS were demonstrated by H-1 NMR in CDCl3 solutions Miktoarm stars formation in the bulk was also confirmed by transmission electronic microscopy

  DOI：

  10.1021/ma101044y