2,5-Bis(4-carbazol-9-ylphenyl)-1,3,4-oxadiazole | 733038-87-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 2,5-Bis(4-carbazol-9-ylphenyl)-1,3,4-oxadiazole
• 英文别名: 2,5-bis(4-carbazol-9-ylphenyl)-1,3,4-oxadiazole
• CAS: 733038-87-4
• 化学式: C₃₈H₂₄N₄O
• 分子量: 552.635
• InChiKey: JKMOQVJSOXWJNR-UHFFFAOYSA-N

物化性质

• 密度：
  1.30±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  43
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  48.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-(9H-carbazol-9-yl)benzoylhydrazine 、 4-(9H-carbazol-9-yl)benzoic acid 在 三氯氧磷 作用下， 反应 5.0h， 生成 2,5-Bis(4-carbazol-9-ylphenyl)-1,3,4-oxadiazole
  参考文献：
  名称：

  Synthesis and properties of iridium complexes based 1,3,4-oxadiazoles derivatives

  摘要：

  A series of iridium complexes with 2,5-diaryl-[1,3,4]-oxadiazole ligands were synthesized and their electrochemical, photophysical, and electroluminescent (EL) properties studied. It was found that electron-withdrawing or donating substituents on the phenyl ring affected the emission maxima. Complex 3, iridium(IR) bis(2,5-bis-(2-hydroxyphenyl)-[1,3,4]oxadiazolato-C-2, N-3) (acetyl acetonate), was characterized by single-crystal X-ray structural determination. Three organic light emitting diodes devices were fabricated, which showed stable green-yellow luminescence. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.11.099

文献信息

• Synthesis and properties of iridium complexes based 1,3,4-oxadiazoles derivatives
  作者：Zhaowu Xu、Yang Li、Xuemei Ma、Xindong Gao、He Tian

  DOI：10.1016/j.tet.2007.11.099

  日期：2008.2

  A series of iridium complexes with 2,5-diaryl-[1,3,4]-oxadiazole ligands were synthesized and their electrochemical, photophysical, and electroluminescent (EL) properties studied. It was found that electron-withdrawing or donating substituents on the phenyl ring affected the emission maxima. Complex 3, iridium(IR) bis(2,5-bis-(2-hydroxyphenyl)-[1,3,4]oxadiazolato-C-2, N-3) (acetyl acetonate), was characterized by single-crystal X-ray structural determination. Three organic light emitting diodes devices were fabricated, which showed stable green-yellow luminescence. (C) 2007 Elsevier Ltd. All rights reserved.