(R)-2-Methyl-butyric acid (S)-2-(2-acetoxy-ethylamino)-4-methoxy-1,5-dimethyl-6-oxo-cyclohexa-2,4-dienyl ester | 112009-66-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (R)-2-Methyl-butyric acid (S)-2-(2-acetoxy-ethylamino)-4-methoxy-1,5-dimethyl-6-oxo-cyclohexa-2,4-dienyl ester
• CAS: 112009-66-2
• 化学式: C₁₈H₂₇NO₆
• 分子量: 353.415
• InChiKey: RYGUAVIWYDWURX-ZMZPIMSZSA-N

反应信息

• 作为产物：
  描述：

  乙酸酐 、 wasabidienone-E 在 吡啶 作用下， 生成 (R)-2-Methyl-butyric acid (S)-2-(2-acetoxy-ethylamino)-4-methoxy-1,5-dimethyl-6-oxo-cyclohexa-2,4-dienyl ester
  参考文献：
  名称：

  Wasabidienone-E, a New Cyclohexadienone Derivative Containing Hydroxyethylamino Group, from Potato Culture Solution ofPhoma wasabiaeYokogi

  摘要：

  Wasabidienone-E, a new cyclohexadienone derivative containing hydroxyethylamino group, has been isolated from the potato culture solution, and its structure was determined to be 5-(2-hydroxyethylamino)-3-methoxy-2,6-dimethyl-(6R*)-[(2R*)-2-methylbutyryloxy]-2,4-cyclohexadien-1-one by spectroscopic analysis and chemical transformation.

  DOI：

  10.1246/cl.1987.815