trans-Δ²-Buten-1,4-dicarbonsaeure-diamid | 25129-30-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: trans-Δ²-Buten-1,4-dicarbonsaeure-diamid
• 英文别名: hex-3t-enediamide；hex-3-enediamide；Hex-3t-endiamid；Hex-3-endiamid；beta-Hydromuconamide；(E)-hex-3-enediamide
• CAS: 25129-30-0
• 化学式: C₆H₁₀N₂O₂
• 分子量: 142.158
• InChiKey: MQNQJAWLPVZCKN-OWOJBTEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.4
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  86.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (E)-己-3-烯二腈 在 硫酸 作用下， 生成 trans-Δ²-Buten-1,4-dicarbonsaeure-diamid
  参考文献：
  名称：

  Piepenbrink, Justus Liebigs Annalen der Chemie, 1951, vol. 572, p. 83,91

  摘要：

  DOI：

文献信息

• FLUOROSURFACTANTS
  申请人：MERCK PATENT GMBH

  公开号：US20150246875A1

  公开（公告）日：2015-09-03

  The present invention relates to novel compounds containing fluorinated end groups, to the use thereof as surface-active substances, and to compositions comprising these compounds.

  本发明涉及含氟末端基团的新型化合物，以其作为表面活性物质的用途，以及包含这些化合物的组合物。
• METHOD FOR PRODUCING CARBAMATE COMPOUND
  申请人：Ube Industries, Ltd.

  公开号：EP2325167A1

  公开（公告）日：2011-05-25

  A task of the present invention is to provide a process for preparation a carbamate compound using a carbonic acid ester and an amide compound in the presence of a basic compound(s), wherein the process is a novel industrial method which is advantageous in that the reaction rate is faster than conventional and the by-produced ester compound can be recovered, and the present invention is directed to a method comprising reacting an amide compound represented by the formula (1) with a carbonic acid ester represented by the formula (2) in the presence of a basic compound(s) to obtain a carbamate compound represented by the formula (3).

  本发明的任务是提供一种在碱性化合物存在下使用碳酸酯和酰胺化合物制备氨基甲酸 酯化合物的工艺，其中该工艺是一种新颖的工业方法，其优点是反应速率比传统方法快， 且副生成的酯化合物可以回收、本发明涉及一种方法，包括在碱性化合物存在下，使式（1）代表的酰胺化合物与式（2）代表的碳酸酯反应，得到式（3）代表的氨基甲酸酯化合物。
• METHODS OF MAKING ORGANIC COMPOUNDS BY METATHESIS
  申请人：Elevance Renewable Sciences, Inc.

  公开号：EP3281931A1

  公开（公告）日：2018-02-14

  Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.

  本发明描述了通过偏合成化学制造有机化合物的方法。本发明的方法特别适用于从可再生原料（如天然油）中提取的起始组合物开始制造工业上重要的有机化合物。这些方法利用与烯烃化合物的交叉甲基化步骤，生成具有预定双键位置的官能化烯中间体。一旦分离出来，官能化烯中间体可进行自甲基化或交叉甲基化（例如与第二种官能化烯），以生产所需的有机化合物或其前体。该方法可用于制造双官能团有机化合物，如二酸、二酯、二羧酸盐、酸/酯、酸/胺、酸/醇、酸/醛、酸/酮、酸/卤化物、酸/腈、酯/胺、酯/醇、酯/醛、酯/酮、酯/卤化物、酯/腈等。
• Ruhemann; Blackman, Journal of the Chemical Society, 1890, vol. 57, p. 372
  作者：Ruhemann、Blackman

  DOI：——

  日期：——
• Encapsulated Michael addition catalyst
  申请人：Rohm and Haas Company

  公开号：EP1813630B1

  公开（公告）日：2010-03-03