[Cu(η3-(2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine)(N3)][ClO4] | 616234-61-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Cu(η3-(2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine)(N3)][ClO4]
• CAS: 616234-61-8
• 化学式: C₁₃H₁₅CuN₆*ClO₄
• 分子量: 418.299
• InChiKey: RCQCYOSNNOQFML-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine 、 sodium azide 以 甲醇 为溶剂， 以70%的产率得到[Cu(η3-(2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine)(N3)][ClO4]
  参考文献：
  名称：

  Copper(II) azido complexes containing trinitrogen ligands: [Cu(η3-L)(N3)]2[Cu2Cl2(N3)4] [L=2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine], a tridimensional network of cationic and anionic copper complexes

  摘要：

  A series of copper(II) azido complexes containing a tridentate trinitrogen ligand, [Cu(eta(3)-L)(N-3)](+) [L = 2,6-bis(3,4-dihydro-2H-pyrrol-5-yl)pyridine] as well as [Cu(eta(3)-R,S-LH4)(N-3)](+), [Cu(eta(3)-S,S-LH4)(N-3)](+) and [Cu(eta(3)-R,R-LH4)(N-3)](+) [LH4 = 2,6-bis(pyrrolidin-2-yl)pyridine] have been synthesised from Cu(ClO4)(2).6 H2O, NaN3 and the corresponding tridentate ligand and crystallised from methanol as the perchlorate salts. The single crystal X-ray structure analyse show these complexes to form one-dimensional networks by Cu...N(azide) intermolecular interactions, depending on the conformation of the tridentate ligand. In the case of L, an excess of sodium azide leads to the formation of the salt [Cu(eta(3)-L)(N-3)](2)[Cu2Cl2(N-3)(4)], the crystal structure analysis of which reveals a surprising tridimensional network of cationic and anionic copper(II) complexes linked by Cu...N(azide) and Cu...N(L) interactions. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00055-0