4-[3-(4-Methoxyphenoxy)propoxy]benzaldehyde | 177904-41-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[3-(4-Methoxyphenoxy)propoxy]benzaldehyde
• CAS: 177904-41-5
• 化学式: C₁₇H₁₈O₄
• 分子量: 286.328
• InChiKey: JZCGEBBPQOEIME-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-[3-(4-Methoxyphenoxy)propoxy]benzaldehyde 在 盐酸 作用下， 以 1,4-二氧六环 、 水 为溶剂， 生成 1,4-Bis-chloromethyl-2-methoxy-5-(3-{4-[(E)-2-(4-nitro-phenyl)-vinyl]-phenoxy}-propoxy)-benzene
  参考文献：
  名称：

  Synthesis of Poly(1,4-Phenylenevinylene) Derivatives Containing NLO Chromophore within Side Chains

  摘要：

  Poly(1,4-phenylenevinylene) derivative, 58-poly(NO2STMPV-co-IMPV), consisting of poly[2-methoxy-5-{3-(4-nitrostilben-4'-yl-oxy)propoxy}phenylenevinylene] (poly(NO2STMPV)) and poly(2-isopropoxy-5-methoxy-1,4-phenylenevinylene) (poly(IMPV)) was synthesized through the Wessling's precursor method. Films of the precursor copolymers were eliminated either by way of thermal treatment or using strong acidic conditions. The electrical conductivities of FeCl3-doped 58-poly(NO2STMPV-co-IMPV) were found to be between 10(-1)-10(-4) S/cm. The second-order nonlinear optical susceptibility (d(33)) of this copolymer was about 2.0 pm/V.

  DOI：

  10.1080/10587259608040307
• 作为产物：
  描述：

  3-(4-甲氧基苯氧基)丙醇 在 potassium carbonate 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成 4-[3-(4-Methoxyphenoxy)propoxy]benzaldehyde
  参考文献：
  名称：

  Synthesis of Poly(1,4-Phenylenevinylene) Derivatives Containing NLO Chromophore within Side Chains

  摘要：

  Poly(1,4-phenylenevinylene) derivative, 58-poly(NO2STMPV-co-IMPV), consisting of poly[2-methoxy-5-{3-(4-nitrostilben-4'-yl-oxy)propoxy}phenylenevinylene] (poly(NO2STMPV)) and poly(2-isopropoxy-5-methoxy-1,4-phenylenevinylene) (poly(IMPV)) was synthesized through the Wessling's precursor method. Films of the precursor copolymers were eliminated either by way of thermal treatment or using strong acidic conditions. The electrical conductivities of FeCl3-doped 58-poly(NO2STMPV-co-IMPV) were found to be between 10(-1)-10(-4) S/cm. The second-order nonlinear optical susceptibility (d(33)) of this copolymer was about 2.0 pm/V.

  DOI：

  10.1080/10587259608040307

文献信息

• Synthesis of Poly(1,4-Phenylenevinylene) Derivatives Containing NLO Chromophore within Side Chains
  作者：Ki-Jeong Moon、Kwang-Sup Lee、Hong-Ku Shim

  DOI：10.1080/10587259608040307

  日期：1996.4

  Poly(1,4-phenylenevinylene) derivative, 58-poly(NO2STMPV-co-IMPV), consisting of poly[2-methoxy-5-3-(4-nitrostilben-4'-yl-oxy)propoxy}phenylenevinylene] (poly(NO2STMPV)) and poly(2-isopropoxy-5-methoxy-1,4-phenylenevinylene) (poly(IMPV)) was synthesized through the Wessling's precursor method. Films of the precursor copolymers were eliminated either by way of thermal treatment or using strong acidic conditions. The electrical conductivities of FeCl3-doped 58-poly(NO2STMPV-co-IMPV) were found to be between 10(-1)-10(-4) S/cm. The second-order nonlinear optical susceptibility (d(33)) of this copolymer was about 2.0 pm/V.