potassium;[methoxycarbonyl(methyl)amino]-nitroazanide | 135516-78-8

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: potassium;[methoxycarbonyl(methyl)amino]-nitroazanide
• CAS: 135516-78-8
• 化学式: C₃H₆N₃O₄*K
• 分子量: 187.197
• InChiKey: WNGWFWBIFHRQSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.83
• 重原子数：
  11.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  86.78
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  methyl N-[methoxycarbonyl(methyl)amino]-N-nitrocarbamate 生成 potassium;[methoxycarbonyl(methyl)amino]-nitroazanide
  参考文献：
  名称：

  KALININ, A. V.;APASOV, EH. T.;IOFFE, S. L.;TARTAKOVSKIJ, V. A., IZV. AN CCCP. CEP. XIM.,(1991) N, S. 1108-1114

  摘要：

  DOI：

文献信息

• N-nitrohydrazines and their salts
  作者：A. V. Kalinin、�. T. Apasov、S. L. Ioffe、V. A. Tartakovskii

  DOI：10.1007/bf00961361

  日期：1991.5

  A method was developed for the synthesis of functionally substituted N-nitrohydrazines by nonacid nitration of the respective silylhydrazines. It was shown that the stability of these compounds increases with increase in the number of electronegative substituents. The first representative of N,N'-dinitrohydrazines, i.e., N,N'-dinitro-N,N'-diacetylhydrazine, was synthesized. Some of the obtained N-nitrohydrazines are characterized by dissociation with the formation of diazenes. The action of nucleophilic reagents on functionally N,N'-disubstituted N-methyl-N'-nitrohydrazines gave the salts of N-nitrohydrazines.