5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(II) | 101032-32-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(II)
• CAS: 101032-32-0
• 化学式: C₁₈H₁₈MnN₂O₄
• 分子量: 381.29
• InChiKey: FTPGWDOAAXWZLE-BYCVLTJGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ferrocenium hexafluorophosphate 、 5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(II) 以 乙腈 为溶剂， 以40%的产率得到5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(III)(hexafluorophosphate)
  参考文献：
  名称：

  烯烃与阳离子（salen）锰（III）配合物的环氧化。取代基对催化活性的调节

  摘要：

  增强 d'activite avec des substituants 吸引力 d'electrons (dichloro ou dinitro)

  DOI：

  10.1021/ja00269a029
• 作为产物：
  描述：

  bis-(2-hydroxy-5-methoxy-benzylidene)-ethylene-diamine 、 manganese (II) acetate tetrahydrate 在 KOH 作用下， 以 甲醇 、 乙醇 为溶剂， 以80%的产率得到5,5'-dimethoxy-N,N'-ethylenebis(salicylideneaminato) manganese(II)
  参考文献：
  名称：

  Dual pathways for manganese catalysis of olefin oxidation with alkyl hydroperoxides

  摘要：

  DOI：

  10.1016/0304-5102(86)85086-6

文献信息

• Influence of the nature of the metal ion on the rate of reduction of coordinated azomethine group
  作者：A. A. Medzhidov、S. G. Mamedova、A. Aydin、B. Yalcin、S. Tascioglu、E. Kaki

  DOI：10.1134/s1070363207100155

  日期：2007.10

  The kinetics of reduction of the azomethine bond in various Schiff bases and their transition metal complexes with sodium borohydride in dimethylformamide and ethanol solutions was studied. The reduction rate depends on both the structure of the starting Schiff bases and the nature of the metal ion. In transition metal N-phenylsalicylaldiminates, the rate of reduction of the azomethine group increases in the order Zn(II) < Ni(II) < Cu(II) < Co(II) < VO(II) < Mn(II). Similar trend is observed in other series of metal complexes with Schiff bases. The revealed trends are opposite to the Irving-Williams series of stability of complexes. This fact suggests that the major factor affecting the rate of reduction of the coordinated azomethine bond is the strength of its bonding with the metal ion. Depending on particular metal ion, the complexation can either decelerate or accelerate the reduction.