Ru(TTP)(ppyr)₂ | 1551161-25-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Ru(TTP)(ppyr)₂
• 英文别名: Ru(tetratolylporphyrin)(2-(pyrid-2-yl)pyrazine)₂
• CAS: 1551161-25-1
• 化学式: C₆₆H₅₀N₁₀Ru
• 分子量: 1084.26
• InChiKey: QJFVCUVDPMBAJY-KDTBAHQYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 Ru(TTP)(ppyr)₂ 在 air 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以80%的产率得到Ru(TTP){(ppyr)Pd(Me)Cl}₂
  参考文献：
  名称：

  Synthesis of trinuclear Pd–Ru–Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region

  摘要：

  Ru-porphyrin complexes with pyridylpyrazine as metal coordination sites were synthesized. Introduction of Pd-alkyl units to the binding site led to the formation of a novel Pd-Ru-Pd trinuclear complex. The metalation causes drastic changes in the electrochemical and photophysical properties. The trinuclear complex exhibited a prominent metal-to-axial ligand charge transfer band in the visible region due to small energy gap between the Ru-based HOMO and the axial ligand-based LUMO. These changes resulted in the drastic color change from orange to green. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.12.008
• 作为产物：
  描述：

  μ-O-[Ru(TTP)OEt]₂ 、 2-(pyridin-2-yl)pyrazine 在 sodium tetrahydroborate 作用下， 以 四氢呋喃 为溶剂， 以65%的产率得到Ru(TTP)(ppyr)₂
  参考文献：
  名称：

  Synthesis of trinuclear Pd–Ru–Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region

  摘要：

  Ru-porphyrin complexes with pyridylpyrazine as metal coordination sites were synthesized. Introduction of Pd-alkyl units to the binding site led to the formation of a novel Pd-Ru-Pd trinuclear complex. The metalation causes drastic changes in the electrochemical and photophysical properties. The trinuclear complex exhibited a prominent metal-to-axial ligand charge transfer band in the visible region due to small energy gap between the Ru-based HOMO and the axial ligand-based LUMO. These changes resulted in the drastic color change from orange to green. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.12.008