{gold(III)(1-thia-4,7-diazacyclononane)Cl2}Cl | 133529-88-1

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: {gold(III)(1-thia-4,7-diazacyclononane)Cl2}Cl
• CAS: 133529-88-1
• 化学式: C₆H₁₄AuCl₂N₂S*Cl
• 分子量: 449.582
• InChiKey: PXWCFKLAMXGEGE-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  chloroauric acid 、 1-Thia-4,7-diazacyclononan 以 甲醇 为溶剂， 以50%的产率得到{gold(III)(1-thia-4,7-diazacyclononane)Cl2}Cl
  参考文献：
  名称：

  Binding of the late transition metal ions to the mixed N2S donor macrocyclic ligand 1-thia-4,7-diazacyclononane (= L1). X-ray crystal structures of [PtIV(L1)Br3]Br0.5·2H2O, [AuIII(L1)Cl2][AuCl4] and [Ag4(L1)4](CF3SO3)4

  摘要：

  Complexes of the nine-membered macrocyclic ligand 1-thia-4,7-diazacyclononane (L1) with platinum(IV), gold(III) and silver(I) have been prepared and the X-ray crystal structures of [Pt(IV)(L1)Br3]Br0.5Cl0.5.2H2O (1a), [Au(III)(L1)Cl2][AuCl4] (2a) and [Ag4(L1)4](CF3SO3)4 (3a) determined. In the octahedral cation of 1a the ligand is bound facially. Complex 2a contains a planar AuCl2N2 unit and the thioether group is weakly donating [Au-S = 2.973(3) angstrom] to an axial site. In 3a, four AgL1 units are bridged by thioether groups to a centrosymmetrical [Ag4(L1)4]4+ tetramer. The exodentate Ag-S [2.403(2) and 2.415(2) angstrom] bonds are rather short.

  DOI：

  10.1016/s0277-5387(00)83541-x