N,N'-bis(4'-bromophenyl)-1,6,7,12-tetra[4-(1,1,3,3-tetramethylbutyl)phenoxy]perylene-3,4,9,10-tetracarboxdiimide | 344454-74-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis(4'-bromophenyl)-1,6,7,12-tetra[4-(1,1,3,3-tetramethylbutyl)phenoxy]perylene-3,4,9,10-tetracarboxdiimide
• 英文别名: 7,18-Bis(4-bromophenyl)-11,14,22,26-tetrakis[4-(2,4,4-trimethylpentan-2-yl)phenoxy]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone；7,18-bis(4-bromophenyl)-11,14,22,26-tetrakis[4-(2,4,4-trimethylpentan-2-yl)phenoxy]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2(26),3,5(25),9,11,13,15,20,23-decaene-6,8,17,19-tetrone
• CAS: 344454-74-6
• 化学式: C₉₂H₉₆Br₂N₂O₈
• 分子量: 1517.59
• InChiKey: BSIJZZXGAKHFHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  27.9
• 重原子数：
  104
• 可旋转键数：
  22
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  112
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  对特辛基苯酚 、 N,N'-bis(4'-bromophenyl)-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxdiimide 在 potassium carbonate 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 24.0h， 以95%的产率得到N,N'-bis(4'-bromophenyl)-1,6,7,12-tetra[4-(1,1,3,3-tetramethylbutyl)phenoxy]perylene-3,4,9,10-tetracarboxdiimide
  参考文献：
  名称：

  Attaching Perylene Dyes to Polyfluorene:  Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers

  摘要：

  The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the emission to come solely from the dye units. Efficient LEDs have been made from the copolymers with dyes in the mainchain.

  DOI：

  10.1021/ja0205784

文献信息

• [EN] FLUORENE-PERYLENE COPOLYMERS AND USES THEREOF<br/>[FR] COPOLYMERES FLUORENE-PERILENE ET UTILISATION DE CEUX-CI
  申请人：CAMBRIDGE DISPLAY TECH LTD

  公开号：WO2001042331A1

  公开（公告）日：2001-06-14

  A statistical copolymer of formula (I) is provided wherein: A represents an end-capping unit; B is a moiety of formula (II) or (III), wherein each of R?1 and R2¿ is hydrogen, alkyl, haloalkyl, alkoxy, alkoxyalkyl, aryl and aralkyl; C is a perylene-containing moiety of formula (IV), wherein each of a1, a2, a3 and a4 is 0 or 1, each of b3, b4, b5 and b6 is 0, 1 or 2, each of X?1, X2, X3 and X4¿ is a single bond or a linking unit, and each of R?3, R4, R5 and R6¿ is hydrogen, alkyl, haloalkyl, alkoxy, alkoxyalkyl, aryl, aryloxy or aralkyl; and the ratio x:y is from 80:20 to 99.9:0.1. A kit for the synthesis of the copolymers of the invention and electroluminescent devices incorporating said copolymers are also provided.
• Attaching Perylene Dyes to Polyfluorene:  Three Simple, Efficient Methods for Facile Color Tuning of Light-Emitting Polymers
  作者：Christophe Ego、Dirk Marsitzky、Stefan Becker、Jingying Zhang、Andrew C. Grimsdale、Klaus Müllen、J. Devin MacKenzie、Carlos Silva、Richard H. Friend

  DOI：10.1021/ja0205784

  日期：2003.1.1

  The emission color of fluorene-based polymers can be facilely tuned across the whole visible spectrum by copolymerization with perylene dyes. Methods are demonstrated for incorporation of the dyes in the polymer mainchain, at the chain termini, or as side chains. Efficient energy transfer causes the emission to come solely from the dye units. Efficient LEDs have been made from the copolymers with dyes in the mainchain.