1-Hydroperoxy-1-(1-hydroperoxy-3,3,5-trimethylcyclohexyl)peroxy-3,3,5-trimethylcyclohexane | 56671-78-4

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 1-Hydroperoxy-1-(1-hydroperoxy-3,3,5-trimethylcyclohexyl)peroxy-3,3,5-trimethylcyclohexane
• CAS: 56671-78-4
• 化学式: C₁₈H₃₄O₆
• 分子量: 346.464
• InChiKey: LZPNJJZQYFTSHV-UHFFFAOYSA-N

物化性质

• 熔点：
  124-127 °C
• 沸点：
  433.6±25.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3,3,5-三甲基环己酮 在 硫酸 、 双氧水 作用下， 以 苯 为溶剂， 生成 1-Hydroperoxy-1-(1-hydroperoxy-3,3,5-trimethylcyclohexyl)peroxy-3,3,5-trimethylcyclohexane
  参考文献：
  名称：

  An Improved Synthesis of "Mixed" Alkanone Triperoxides

  摘要：

  DOI：

  10.1055/s-1975-23765

文献信息

• Amino-group-containing polymer (salt) and production process therefor
  申请人：Nippon Shokubai Co., Ltd.

  公开号：US20010014722A1

  公开（公告）日：2001-08-16

  The present invention provides a novel amino-group-containing polymer (salt) and a production process therefor wherein the amino-group-containing polymer (salt) is a product by a process including the step of introducing amino groups into a grafted polymer having a polyether skeleton, and can make good use of the reactivity or cationic property of at least primary amino groups and further, according to circumstances, secondary amino groups, and further can display various performances, such as curability useful for various uses and adsorbency onto films or fibers. The novel amino-group-containing polymer (salt) is a product by a process including the steps of: carrying out a graft polymerization of a monoethylenically unsaturated monomer component onto a polyether compound, wherein the monoethylenically unsaturated monomer component includes an unsaturated carboxylic monomer as an essential component, and wherein the polyether compound has a specific repeating unit in a ratio of not less than 30 mol % and has a number-average molecular weight of not less than 150; and introducing amino groups by carrying out a ring-opening addition of an alkylenimine to at least a part of carboxyl group portions of the monoethylenically unsaturated monomer component which has been graft-polymerized onto the polyether compound, wherein at least a part of the amino groups might be neutralized with an acid.

  本发明提供了一种新型的含氨基聚合物（盐）及其生产工艺，其中该含氨基聚合物（盐）是通过将氨基引入具有聚醚骨架的接枝聚合物而得到的产品，并且可以充分利用至少一级氨基的反应性或阳离子性质，根据情况还可以利用二级氨基，并且还可以表现出各种性能，例如可用于各种用途的可固化性和对薄膜或纤维的吸附性能。该新型含氨基聚合物（盐）是通过以下步骤得到的产品：将单乙烯不饱和单体组分接枝聚合到聚醚化合物上，其中单乙烯不饱和单体组分包括不饱和羧酸单体作为必要组分，聚醚化合物具有特定的重复单元，在不少于30摩尔％的比例下，并且具有不少于150的数均分子量；通过对已经接枝聚合到聚醚化合物上的单乙烯不饱和单体组分的羧基部分中的至少一部分进行环开口加成，引入氨基，其中至少一部分氨基可能被酸中和。
• Polymerizable composition
  申请人：Fujimaki Kazuhiro

  公开号：US20050106495A1

  公开（公告）日：2005-05-19

  A polyaerizable composition comprising: (A) a compound which causes at least one of decarboxylation and dehydration by heat; (B) a radical initiator; (C) a compound having at least one ethylenically unsaturated bond; and (D) an infrared ray absorber.

  一种可聚合的组合物，包括：（A）一种通过热引起至少一种脱羧和脱水的化合物; （B）一种自由基引发剂; （C）至少具有一个乙烯基不饱和键的化合物; 和（D）一种红外线吸收剂。
• Polymerizable composition and planographic printing plate precursor
  申请人：Taguchi Yoshinori

  公开号：US20060051701A1

  公开（公告）日：2006-03-09

  The present invention provides a polymerizable composition comprising (A) a compound represented by the following formula (I), (B) an infrared absorbent, and (C) a compound having at least one addition-polymerizable ethylenically unsaturated bond, and a negative planographic printing plate precursor having a recording layer containing the polymerizable composition. In the formula (I), R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 each independently represent a hydrogen atom or a monovalent organic group; and X − represents an anion.

  本发明提供了一种可聚合组成物，包括（A）以下式子（I）所代表的化合物，（B）红外吸收剂和（C）至少具有一个加成聚合乙烯基不饱和键的化合物，以及具有包含可聚合组成物的记录层的负电平面印刷版前体。在式（I）中，R1，R2，R3，R4，R5和R6各自独立地代表氢原子或一价有机基；X-代表负离子。
• LASER-DECOMPOSABLE RESIN COMPOSITION AND PATTERN-FORMING MATERIAL USING THE SAME
  申请人：SUGASAKI Atsushi

  公开号：US20080038663A1

  公开（公告）日：2008-02-14

  A laser-decomposable resin composition contains: a compound including at least one structure selected from a carboxyl group and a carboxylic acid anhydride structure and at least one hetero atom selected from N, S and O atoms other than the structure; and a binder polymer.

  一种可激光分解的树脂组合物，包括：一种化合物，其中包括至少一种结构，所述结构从羧基和羧酸酐结构中选择至少一种，并且还包括至少一种异原子，所述异原子选自N、S和O原子以外的结构；以及一种粘合剂聚合物。
• PHOTOCURABLE COMPOSITION
  申请人：Tanaka Masayuki

  公开号：US20140045963A1

  公开（公告）日：2014-02-13

  [Problem] To provide a photocurable sealing material which exhibits stable physical properties, particularly permanent compression set when subjected to a heat resistance test in an atmosphere of 100 to 150° C., and has a stable applying shape and storage stability. [Solution] A photocurable composition containing components (A) to (C) mentioned below, in which the mass ratio of the component (A) to the component (B) is 3:7 to 8:2; component (A): a compound having a polymer of a (meth)acrylic monomer as a main skeleton and having one (meth)acryl group at each of the both terminals; component (B): a compound having a polymer of a (meth)acrylic monomer as a main skeleton and having one (meth)acryl group at only one terminal; and component (C): a photoinitiator.

  [问题] 提供一种光固化密封材料，其展现稳定的物理特性，特别是在100至150°C的大气中进行耐热性测试时具有稳定的永久压缩性，并具有稳定的应用形状和储存稳定性。 [解决方案] 包含以下组分（A）至（C）的光固化组合物，其中组分（A）与组分（B）的质量比为3:7至8:2；组分（A）：具有（甲基）丙烯酸酯单体聚合物为主骨架并且在两个端部都有一个（甲基）丙烯酰基的化合物；组分（B）：具有（甲基）丙烯酸酯单体聚合物为主骨架并且仅在一个端部有一个（甲基）丙烯酰基的化合物；以及组分（C）：光引发剂。