[(tris(pyrazolyl)methane)W(NO)Br2]BF4 | 913975-00-5

• 英文名称: [(tris(pyrazolyl)methane)W(NO)Br2]BF4
• CAS: 913975-00-5
• 化学式: BF₄*C₁₀H₁₀Br₂N₇OW
• 分子量: 674.698
• InChiKey: AJGQUZFNTJIPMF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(tris(pyrazolyl)methane)W(NO)Br2]BF4 、 三甲氧基磷 在 锌 作用下， 以 not given 为溶剂， 以38%的产率得到[(tris(pyrazolyl)methane)W(NO)Br(P(OMe)3)]BF4
  参考文献：
  名称：

  Development of Group 6 Dearomatization Agents

  摘要：

  A series of complexes having the general formulas [TpM(NO)(L)Br] and [TpmM(NO)(L)Br]BF4 (M = Mo or W and L = a moderate sigma- donor) have been prepared. Variations in L provide access to M(I) complexes having a broad range of electronic and steric properties. Reduction of a limited number of these complexes in the presence of aromatic molecules produces novel complexes with the general formula [TpM(NO)(L)(eta(2)-aromatic)](n+) (n = 0, 1).

  DOI：

  10.1021/om060597c
• 作为产物：
  描述：

  [(tris(pyrazolyl)methane)W(CO)2(NO)]BF4 、 溴 以 1,2-二氯乙烷 为溶剂， 生成 [(tris(pyrazolyl)methane)W(NO)Br2]BF4
  参考文献：
  名称：

  Development of Group 6 Dearomatization Agents

  摘要：

  A series of complexes having the general formulas [TpM(NO)(L)Br] and [TpmM(NO)(L)Br]BF4 (M = Mo or W and L = a moderate sigma- donor) have been prepared. Variations in L provide access to M(I) complexes having a broad range of electronic and steric properties. Reduction of a limited number of these complexes in the presence of aromatic molecules produces novel complexes with the general formula [TpM(NO)(L)(eta(2)-aromatic)](n+) (n = 0, 1).

  DOI：

  10.1021/om060597c