[PdMe(aziridine)(1,2-bis(diphenylphosphino)ethane)](CF3SO3) | 926304-28-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: [PdMe(aziridine)(1,2-bis(diphenylphosphino)ethane)](CF3SO3)
• 英文别名: [(dppe)PdMe(aziridine)](CF3SO3)
• CAS: 926304-28-1
• 化学式: CF₃O₃S*C₂₉H₃₂NP₂Pd
• 分子量: 712.018
• InChiKey: HUOWHIBXCCLZKN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙烯亚胺 、 [PdMe(NCMe)(1,2-bis(diphenylphosphino)ethane)](CF3SO3) 以 四氢呋喃 为溶剂， 以70%的产率得到[PdMe(aziridine)(1,2-bis(diphenylphosphino)ethane)](CF3SO3)
  参考文献：
  名称：

  Synthesis and reactions of heterodinuclear organopalladium–cobalt complexes acting as copolymerization catalyst for aziridine and carbon monoxide

  摘要：

  A series of heterodinuclear acylpalladium-cobalt complexes having a bidentate nitrogen ligand, L-2(RCO)Pd-Co(CO)(4) (L-2 = bpy, R = Me (5), Ph (6); L-2 = tmeda, R = Me (7), Ph (8); L-2 = phen, R = Me (9), Ph (10)) are prepared by metathetical reactions of PdRIL2 with Na+[Co(CO)(4)](-) followed by treatment with CO. These complexes are characterized by NMR and IR spectroscopies and elemental analyses, and the molecular structures of 6, 8, and 9 are determined by X-ray structure analysis. Geometry at Pd is essentially square planar and the Cc atom is considered to have d(10) tetrahedral structure, where cobalt(-I) anion coordinates to palladium(II) cation. Heterodinuclear organopalladium-cobalt complexes are shown to catalyze copolymerization of aziridines and CO under mild conditions. Reaction of (dppe)MePd-Co(CO)(4) (1) with aziridine gives a cationic (aziridine)palladium(II) complex with [CO(CO)(4)](-) anion, [PdMe(aziridine)(dppe)](+)[CO(CO)(4)](-) (13). (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.04.044