2-carboxyisopropylacrylamide | 262609-87-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-carboxyisopropylacrylamide
• 英文别名: 2-carboxyisopropyl acrylamide；3-(Acryloylamino)butanoic acid；3-(prop-2-enoylamino)butanoic acid
• CAS: 262609-87-0
• 化学式: C₇H₁₁NO₃
• 分子量: 157.169
• InChiKey: SPAPYJVTYNJYIJ-UHFFFAOYSA-N

物化性质

• 沸点：
  388.3±34.0 °C(Predicted)
• 密度：
  1.121±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  66.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-carboxyisopropylacrylamide 、 2-叠氮基乙胺 以 二氯甲烷 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  JP5818245

  摘要：

  公开号：
• 作为产物：
  描述：

  2-(benzyloxycarbonyl)isopropyl acrylamide 在 sodium hydroxide 、 乙醚 、 盐酸 、 甲醇 作用下， 反应 1.0h， 生成 2-carboxyisopropylacrylamide
  参考文献：
  名称：

  ACRYLAMIDE DERIVATIVES AND POLYMERS CONTAINING SAID DERIVATIVES

  摘要：

  公开号：

  EP1147076B1

文献信息

• [EN] CONDENSED ISOXAZOLINE DERIVATIVES AND THEIR USE AS HERBICIDES<br/>[FR] DÉRIVÉS D'ISOXAZOLINE CONDENSÉS ET LEUR UTILISATION COMME HERBICIDES
  申请人：BASF SE

  公开号：WO2021224040A1

  公开（公告）日：2021-11-11

  The invention relates to compounds of formula (I), and their use as herbicides. In said formula, R1 to R6 represent groups such as hydrogen, halo-gen or organic groups such as alkyl, alkenyl, alkynyl, or alkoxy; W is a bicyclic heterocycle; X is a bond or a divalent unit; Y is hydrogen, cyano, hydroxyl or a linear or cyclic organic group. The invention further refers to a composition comprising such compound and to the use thereof for controlling unwanted vegetation.

  该发明涉及公式（I）的化合物，以及它们作为除草剂的用途。在该公式中，R1到R6代表诸如氢、卤素或有机基团（如烷基、烯基、炔基或烷氧基）等基团；W是一个双环杂环；X是一个键或二价基团；Y是氢、氰基、羟基或线性或环状有机基团。该发明还涉及包含这种化合物的组合物以及将其用于控制不受欢迎的植被。
• Phenylboronic Acid Monomer and Phenylboronic Acid Polymer
  申请人：Matsumoto Akira

  公开号：US20120283403A1

  公开（公告）日：2012-11-08

  Disclosed are a phenylboronic acid monomer and a phenylboronic acid polymer, each of which can have a pKa value suitable for the use under physiological environments and can be used for various applications. The pheanylboronic acid monomer has a structure represented by formula (13) and therefore has high hydrophilicity, can have a satisfactorily low pKa value when the phenyl ring is fluorinated, and can have a polymerizable unsaturated bond. The phenylboronic acid monomer has high hydrophilicity at a pKa value of 7.4 or less which is a physiological level, and can be polymerized with a wide variety of monomers to produce polymers suitable for the intended purposes.

  本发明涉及一种苯基硼酸单体和苯基硼酸聚合物，它们的pKa值适用于生理环境下的各种应用。苯基硼酸单体具有公式（13）所表示的结构，因此具有高亲水性，在苯环氟化时可以具有令人满意的低pKa值，并且可以具有可聚合的不饱和键。苯基硼酸单体在pKa值为7.4或更低的生理水平下具有高亲水性，并且可以与各种单体聚合，以生产适用于预期用途的聚合物。
• PHENYLBORONIC ACID MONOMER AND PHENYLBORONIC ACID POLYMER
  申请人：National Institute for Materials Science

  公开号：EP2522679A1

  公开（公告）日：2012-11-14

  Disclosed are a phenylboronic acid monomer and a phenylboronic acid polymer, each of which can have a pKa value suitable for the use under physiological environments and can be used for various applications. The pheanylboronic acid monomer has a structure represented by formula (13) and therefore has high hydrophilicity, can have a satisfactorily low pKa value when the phenyl ring is fluorinated, and can have a polymerizable unsaturated bond. The phenylboronic acid monomer has high hydrophilicity at a pKa value of 7.4 or less which is a physiological level, and can be polymerized with a wide variety of monomers to produce polymers suitable for the intended purposes.

  本发明公开了一种苯硼酸单体和一种苯硼酸聚合物，每种单体和聚合物的 pKa 值均适合在生理环境下使用，并可用于各种用途。苯硼酸单体具有由式（13）表示的结构，因此具有高亲水性，当苯基环被氟化时，可具有令人满意的低 pKa 值，并可具有可聚合的不饱和键。苯基硼酸单体具有高亲水性，pKa 值为 7.4 或低于生理水平，可与多种单体聚合，生产出适合预期目的的聚合物。
• POLYMER PARTICLES WITH A GRADIENT COMPOSITION AND METHODS OF PRODUCTION THEREOF
  申请人：Waters Technologies Corporation

  公开号：US20190322783A1

  公开（公告）日：2019-10-24

  The current invention provides a novel method to synthesize a mono-disperse non-porous polymer particles with a unique gradient composition from the core to the shell. In particular, The present invention offers the flexibility to design the chemical and physical properties of different sections of the particle. This flexibility allows for significant latitude in the design of particles for analyzing a large variety of samples in different fields—through using these particles in different chromatography techniques including, but not limited to, ion exchange HPLC (e.g., bio-separation at different modes), reversed-phase HPLC, narrow bore and capillary HPLC, hydrophilic/hydrophobic interaction liquid chromatography, capillary electrochromatography separation, and two dimensional liquid chromatography.
• US5990334A
  申请人：——

  公开号：US5990334A

  公开（公告）日：1999-11-23