| 1313480-86-2

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• CAS: 1313480-86-2
• 化学式: C₁₀H₁₉Al
• 分子量: 166.242
• InChiKey: KMABVZWIWWWPSG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.56
• 重原子数：
  11.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  在 双氧水 作用下， 以 氯仿 、 甲苯 为溶剂， 反应 1.5h， 生成 2,3-diethyl-1-butylphosphol-2-ene 1-oxide
  参考文献：
  名称：

  Targeted synthesis of 2,3-disubstituted 2-phospholenes using catalytic cycloalumination of acetylenes

  摘要：

  A preparative one-pot method for the synthesis of 2,3-dialkyl-substituted phosphol-2-enes by catalytic cycloalumination of symmetric acetylenes with AlEt3 catalyzed by Cp2ZrCl2 is developed. The reaction gives the corresponding aluminacyclopentenes, which then react in situ with phosphorus dihalides. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.05.029
• 作为产物：
  描述：

  4-辛炔 、 三乙基铝 在 二氯二茂锆 作用下， 以 正己烷 为溶剂， 反应 8.0h， 生成
  参考文献：
  名称：

  Synthesis of substituted 2,3-dihydro-1H-boroles by transmetalation of aluminacyclopent-2-enes with BF3·Et2O

  摘要：

  A procedure was developed for selective synthesis of 4,5-dialkyl-1-fluoro-2,3-dihydro-1H-boroles via transmetalation of the corresponding aluminacyclopent-2-enes with BF3 center dot Et2O. 4,5-Dialkyl-1-fluoro-2,3-dihydro-1H-boroles were isolated as complexes with BEtF2. 4-Alkyl-5-dimethylaminomethyl-1-fluoro-2,3-dihydro-1H-boroles were synthesized for the first time.

  DOI：

  10.1134/s1070428012060024

文献信息

• Synthesis of halogen-substituted borolanes and 2,3-dihydro-1H-boroles by reactions of aluminacarbocycles with boron trichloride and boron tribromide
  作者：L. I. Khusainova、L. O. Khafizova、T. V. Tyumkina、U. M. Dzhemilev

  DOI：10.1134/s1070428014030014

  日期：2014.3

  A selective procedure has been developed for the synthesis of 1-chloro(bromo)-substituted borolanes and 2,3-dihydro-1H-boroles by reaction of aluminacarbocycles with boron trihalides BX3 (X = Cl, Br). 3-Substituted 1-chloro(bromo)borolanes and 2,3-dihydro-1H-boroles have been isolated as individual substances, and their structure has been determined.

  通过铝碳环化合物与三卤化硼BX 3（X = Cl，Br）的反应，已经开发出一种选择性程序，用于合成1-氯（溴）取代的硼烷和2,3-二氢-1 H-硼烷。已分离出3-取代的1-氯（溴）硼烷和2,3-二氢-1 H-硼酸酯作为单独的物质，并已确定了它们的结构。