[(η6-C6Me6)RuCl(4,7-dihydroxy-1,10-phenanthroline)]Cl | 681176-03-4

• 英文名称: [(η6-C6Me6)RuCl(4,7-dihydroxy-1,10-phenanthroline)]Cl
• CAS: 681176-03-4
• 化学式: C₂₄H₂₆ClN₂O₂Ru*Cl
• 分子量: 546.459
• InChiKey: NZZXDXXGIFCPMJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η6-C6Me6)RuCl(4,7-dihydroxy-1,10-phenanthroline)]Cl 、 potassium hydroxide 以 水 为溶剂， 生成 [(η6-C6Me6)RuCl(4,7-(O)2-1,10-phenanthroline)]K
  参考文献：
  名称：

  Half-Sandwich Complexes with 4,7-Dihydroxy-1,10-phenanthroline:  Water-Soluble, Highly Efficient Catalysts for Hydrogenation of Bicarbonate Attributable to the Generation of an Oxyanion on the Catalyst Ligand

  摘要：

  Half-sandwich Ru(II), Ir(III), and Rh(III) complexes with 4,7-dihydroxy-1,10-phenanthroline are highly efficient catalysts for hydrogenation of bicarbonate in alkaline aqueous solution without an amine additive. The generation of an oxyanion by deprotonation of the two hydroxy substituents on the catalyst ligand caused a dramatic enhancement of catalytic activity, due to its strong electron-donating ability, as well as imparting water solubility.

  DOI：

  10.1021/om030382s
• 作为产物：
  描述：

  盐酸 、 [(η6-C6Me6)RuCl(4,7-(O)2-1,10-phenanthroline)]K 以 盐酸 为溶剂， 生成 [(η6-C6Me6)RuCl(4,7-dihydroxy-1,10-phenanthroline)]Cl
  参考文献：
  名称：

  Half-Sandwich Complexes with 4,7-Dihydroxy-1,10-phenanthroline:  Water-Soluble, Highly Efficient Catalysts for Hydrogenation of Bicarbonate Attributable to the Generation of an Oxyanion on the Catalyst Ligand

  摘要：

  Half-sandwich Ru(II), Ir(III), and Rh(III) complexes with 4,7-dihydroxy-1,10-phenanthroline are highly efficient catalysts for hydrogenation of bicarbonate in alkaline aqueous solution without an amine additive. The generation of an oxyanion by deprotonation of the two hydroxy substituents on the catalyst ligand caused a dramatic enhancement of catalytic activity, due to its strong electron-donating ability, as well as imparting water solubility.

  DOI：

  10.1021/om030382s