[bis(2-(2-oxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl)copper(II)] | 626206-54-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [bis(2-(2-oxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl)copper(II)]
• CAS: 626206-54-0
• 化学式: C₂₆H₃₀CuN₆O₈
• 分子量: 618.106
• InChiKey: RVIXKNCTETWESC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2-(2-hydroxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl 在 triethylamine 作用下， 以 甲醇 、 氯仿 为溶剂， 以90%的产率得到[bis(2-(2-oxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl)copper(II)]
  参考文献：
  名称：

  Synthesis of 2-iminonitroxide-substituted phenols and pyridine-3-oles.

  摘要：

  Methods for the synthesis of a new family of nitronylnitroxides, iminonitroxides, and their precursors with 2-hydroxyphenyl or 3-hydroxypyridin-2-yl substituents in the side chain have been developed. Five heterospin chelates of Cu(II) with deprotonated iminonitroxides have been isolated. Their structure and magnetic properties have been studied. In all complexes, ferromagnetic intramolecular exchange interactions take place (J similar to 40-350 cm(-1)) (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00228-6