[Ni(II)(NS)₂] | 72871-83-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Ni(II)(NS)₂]
• 英文别名: [Ni(II)(S-methyl-3-(4-methoxybenzylidine)dithiocarbazate)₂]；bis(S-methyl-β-N-(4-methyloxyphenyl)methylendithiocarbazide)nickel(II)
• CAS: 72871-83-1
• 化学式: C₂₀H₂₂N₄NiO₂S₄
• 分子量: 537.374
• InChiKey: ZPLOLXHWHYBEEZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ni(II)(NS)₂] 在 (C₅H₄N)2 作用下， 以 苯 为溶剂， 生成 bis(s-methyl-N-p-methoxybenzylidenehydrazinecarbodithioate)bis(2,2'-bipyridine)nickel(II)
  参考文献：
  名称：

  含硫配体的金属螯合物对路易斯碱的反应性。第二部分 双（S-甲基-N-亚芳基肼基二硫代硫酸盐）镍（II）螯合物与吡啶和2,2'-联吡啶的反应

  摘要：

  摘要在苯溶液中研究了双（S-甲基-N-亚芳基肼基碳二硫酸酯）镍（II）螯合物与吡啶，3-甲基吡啶，4-甲基吡啶和2,2'-联吡啶的反应。分光光度法测量了形成加合物的稳定性常数和热力学参数。获得的结果表明，具有不相同的吡啶的八面体双加合物的形成，而顺式八面体单加合物是由2,2'-联吡啶与对甲氧基，对甲基和未取代的螯合物反应形成的。然而，对氯衍生物形成五配位单加合物，其中of分子之一表现为身份不明的配体。通过停止流动技术跟踪联吡啶加合物形成的动力学。动力学数据表明五坐标中间体迅速形成，

  DOI：

  10.1016/s0020-1693(00)83770-6
• 作为产物：
  描述：

  4-甲氧基苯甲醛 以 乙醇 为溶剂， 反应 0.83h， 生成 [Ni(II)(NS)₂]
  参考文献：
  名称：

  Synthesis, characterization, and antimicrobial activity of complexes of Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II), and U(VI) containing bidentate Schiff base of [S-methyl-3-(4-methoxybenzylidine)dithiocarbazate]

  摘要：

  A novel bidentate Schiff base containing NS donor sequences was synthesized by condensing S-methyldithiocarbazate (SMDTC) with p-anisaldehyde. A series of complexes of the ligand with Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II) and U(VI) were studied and characterized by various physico-chemical methods. Cu(II), Ni(II) and Zn(II), Pb(II) complexes were four-coordinate with square plannar and tetrahedral geometry respectively. Co(II), Mn(II), and U(VI) complexes were six-coordinate with octahedral geometry. Antimicrobial activity of the prepared complexes was tested as resistance to antimicrobial agents in a wide variety of nosocomial and community-acquired pathogens. The highest antimicrobial activity was detected for the complex Co(II) against candida species.

  DOI：

  10.1134/s1070363215040350

文献信息

• Aly, A. A. M.; Hassan, A. M. A.; Soliman, E. M., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1990, vol. 29, # 8, p. 811 - 814
  作者：Aly, A. A. M.、Hassan, A. M. A.、Soliman, E. M.、El-Shabasy, M.

  DOI：——

  日期：——
• Bis[methyl Nβ-(4-methoxyphenylmethylene)dithiocarbazato]nickel(II)
  作者：H. K. Fun、K. Sivakumar、Y. P. Tian、C. Y. Duan、Z. L. Lu、X. Z. You

  DOI：10.1107/s0108270195015290

  日期：1996.5.15

  The structure of the title compound, [Ni(C10H11-N2OS2)(2)], has been determined at 173 K. There are two independent complex molecules present in the crystal with two slightly different ligand conformations. Both independent Ni atoms lie on inversion centres.
• Adduct formation by nickel(II) complexes of S-methyl hydrazine carbodithioate schiff bases with 2,2′-bipyridyl and 1,10-phenanthroline
  作者：Aly M.A. Hassaan、Ezzat M. Soliman、Ahmed M. El-Roudi

  DOI：10.1016/s0277-5387(00)86445-1

  日期：1989.1
• Yu-Peng, Tian; Chun-Ying, Duan; Zhong-Lin, Lu, Polyhedron, 1996, vol. 15, p. 4415 - 4420
  作者：Yu-Peng, Tian、Chun-Ying, Duan、Zhong-Lin, Lu、Xiao-Zeng, You、Mak, Thomas, C. W.

  DOI：——

  日期：——
• Yu-Peng, Tian; Chun-Ying, Duan; Zhong-Lin, Lu, Polyhedron, <hi>1996</hi>, vol. 15, p. 4415 - 4420
  作者：Yu-Peng, Tian、Chun-Ying, Duan、Zhong-Lin, Lu、Xiao-Zeng, You、Mak, Thomas, C. W.

  DOI：——

  日期：——