[2-Hydroxy-3-[2-hydroxy-3-[2-hydroxy-3-(3-prop-2-enoyloxypropanoyloxy)propoxy]propoxy]propyl] 3-prop-2-enoyloxypropanoate | 1338828-95-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [2-Hydroxy-3-[2-hydroxy-3-[2-hydroxy-3-(3-prop-2-enoyloxypropanoyloxy)propoxy]propoxy]propyl] 3-prop-2-enoyloxypropanoate
• CAS: 1338828-95-7
• 化学式: C₂₁H₃₂O₁₃
• 分子量: 492.477
• InChiKey: RJQYIHOMTWJIFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.3
• 重原子数：
  34
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  184
• 氢给体数：
  3
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  甲基丙烯酸缩水甘油酯 、 [2-Hydroxy-3-[2-hydroxy-3-[2-hydroxy-3-(3-prop-2-enoyloxypropanoyloxy)propoxy]propoxy]propyl] 3-prop-2-enoyloxypropanoate 、 乙酰乙酸乙酯 在 四丁基溴化铵 作用下， 反应 3.0h， 生成
  参考文献：
  名称：

  Michael Acceptor Having Multiple Hydroxyl Groups, and Michael Addition Product Derived Therefrom

  摘要：

  提供的是从具有多个羟基的多功能丙烯酸单体制备的Michael加成产物，允许引入丙烯酸功能团作为Michael受体和Michael给体。该Michael加成产物是一种新颖的多功能化合物，在分子中具有寡聚体和光引发剂基团。由于它可以在标准紫外光固化条件下固化，无需添加光引发剂，因此减少了空气污染或健康问题。因此，通过固化涂层获得了优越的物理性能，而无需表面粘性。此外，其羟基通过异氰酸酯键合或引入丙烯基，允许进行三维交联和分子和组成设计，以改善可扩展性、摩擦、反应性和亲水性，用于自粘附、固化膜的硬度等。因此，可以制备非常有用的多功能或水分散性涂料组合物。

  公开号：

  US20130331600A1
• 作为产物：
  描述：

  glycerol diglycidyl ether 、 β-(丙烯酰氧)丙酸 在 三乙胺 作用下， 反应 4.0h， 以83%的产率得到[2-Hydroxy-3-[2-hydroxy-3-[2-hydroxy-3-(3-prop-2-enoyloxypropanoyloxy)propoxy]propoxy]propyl] 3-prop-2-enoyloxypropanoate
  参考文献：
  名称：

  Michael Acceptor Having Multiple Hydroxyl Groups, and Michael Addition Product Derived Therefrom

  摘要：

  提供的是从具有多个羟基的多功能丙烯酸单体制备的Michael加成产物，允许引入丙烯酸功能团作为Michael受体和Michael给体。该Michael加成产物是一种新颖的多功能化合物，在分子中具有寡聚体和光引发剂基团。由于它可以在标准紫外光固化条件下固化，无需添加光引发剂，因此减少了空气污染或健康问题。因此，通过固化涂层获得了优越的物理性能，而无需表面粘性。此外，其羟基通过异氰酸酯键合或引入丙烯基，允许进行三维交联和分子和组成设计，以改善可扩展性、摩擦、反应性和亲水性，用于自粘附、固化膜的硬度等。因此，可以制备非常有用的多功能或水分散性涂料组合物。

  公开号：

  US20130331600A1

文献信息

• MICHAEL ACCEPTOR HAVING MULTIPLE HYDROXYL GROUPS, AND MICHAEL ADDITION PRODUCT DERIVED THEREFROM
  申请人：Kim Young Chul

  公开号：US20110251338A1

  公开（公告）日：2011-10-13

  Provided is a Michael addition product prepared from a multifunctional acryl monomer having multiple hydroxyl groups allowing introduction of acryl functional groups, as a Michael acceptor, and a Michael donor. The Michael addition product is a novel multifunctional compound having an oligomer and a photoinitiator moiety in the molecule. Since it can be cured under a standard UV curing condition without having to add a photoinitiator, it is reduced to air pollution or health problem. Therefore the superior physical properties were obtained by cured coatings without surface tackiness. In addition, its hydroxyl groups allow, through isocyanate bonding or introduction of acryl groups, 3-dimensional crosslinking and molecular and compositional design for improving expandability, friction, and reactivity and hydrophilicity for self-adhesion, hardness of cured film, or the like. Consequently, a very useful, multifunctional or water-dispersible coating composition may be prepared.
• US8507625B2
  申请人：——

  公开号：US8507625B2

  公开（公告）日：2013-08-13
• Michael Acceptor Having Multiple Hydroxyl Groups, and Michael Addition Product Derived Therefrom
  申请人：Korea Research Institute of Chemical Technology

  公开号：US20130331600A1

  公开（公告）日：2013-12-12

  Provided is a Michael addition product prepared from a multifunctional acryl monomer having multiple hydroxyl groups allowing introduction of acryl functional groups, as a Michael acceptor, and a Michael donor. The Michael addition product is a novel multifunctional compound having an oligomer and a photoinitiator moiety in the molecule. Since it can be cured under a standard UV curing condition without having to add a photoinitiator, it is reduced to air pollution or health problem. Therefore the superior physical properties were obtained by cured coatings without surface tackiness. In addition, its hydroxyl groups allow, through isocyanate bonding or introduction of acryl groups, 3-dimensional crosslinking and molecular and compositional design for improving expandability, friction, and reactivity and hydrophilicity for self-adhesion, hardness of cured film, or the like. Consequently, a very useful, multifunctional or water-dispersible coating composition may be prepared.

  提供的是从具有多个羟基的多功能丙烯酸单体制备的Michael加成产物，允许引入丙烯酸功能团作为Michael受体和Michael给体。该Michael加成产物是一种新颖的多功能化合物，在分子中具有寡聚体和光引发剂基团。由于它可以在标准紫外光固化条件下固化，无需添加光引发剂，因此减少了空气污染或健康问题。因此，通过固化涂层获得了优越的物理性能，而无需表面粘性。此外，其羟基通过异氰酸酯键合或引入丙烯基，允许进行三维交联和分子和组成设计，以改善可扩展性、摩擦、反应性和亲水性，用于自粘附、固化膜的硬度等。因此，可以制备非常有用的多功能或水分散性涂料组合物。