[Co(Cp)2][Rh(F28TPP)] | 300696-93-9

• 英文名称: [Co(Cp)2][Rh(F28TPP)]
• CAS: 300696-93-9
• 化学式: C₁₀H₁₀Co*C₄₄F₂₈N₄Rh
• 分子量: 1408.55
• InChiKey: KILAZEIHVLOFAQ-KGOCWBNTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Co(Cp)2][Rh(F28TPP)] 在 ferrocenium hexafluorophosphate 作用下， 以 苯 为溶剂， 生成 [5,10,15,20-tetrakis(pentafluorophenyl)-2,3,7,8,12,13,17,18-octafluoroporphinato]rhodium(II)
  参考文献：
  名称：

  Reversible Electrochemical Generation of a Rhodium(II) Porphyrin:  Thwarting Disproportionation with Weakly Coordinating Anions

  摘要：

  We report electrochemical generation of a stable Rh(II) porphyrin (Rh-II(F28TPP)) from a four-coordinate Rh(l) precursor [Rh-I (F28TPP)](-) dissolved in weakly coordinating electrolyte solutions. This work provides the first example of an unambiguously reversible one-electron electrochemical oxidation of a Rh-I(por), and demonstrates that electrochemical oxidation can be performed under conditions that are compatible with alkane activation. These studies begin to classify those media capable of supporting a stable Rh-II(por), and those that induce disproportionation.

  DOI：

  10.1021/ic0345830