[Cu(6tbp)Cu(hydroperoxo)](1+) | 943218-64-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Cu(6tbp)Cu(hydroperoxo)](1+)
• CAS: 943218-64-2
• 化学式: C₂₈H₃₁CuN₄O₂
• 分子量: 523.127
• InChiKey: CVMLHBOGYFDHQZ-PHMQUGLBSA-M

反应信息

• 作为产物：
  描述：

  hydrogen (18)O-peroxide 、 [(6tbp)Cu(acetone)][ClO4]2 在 三乙胺 作用下， 以 水 、 丙酮 为溶剂， 生成 [Cu(6tbp)Cu(hydroperoxo)](1+)
  参考文献：
  名称：

  Aryl Hydroxylation from a Mononuclear Copper-Hydroperoxo Species

  摘要：

  Mononuclear Cu-II--OOH entities or derived species have been seriously considered as important in chemical or biochemical oxidations. Yet, synthetic chemistry investigations have thus far revealed they have very limited substrate reactivity. Here, a significant aryl hydroxylation reaction occurs from a hydroperoxocopper(II) complex possessing a tripodal tetradentate ligand with appended aryl substituent. A phenolate-Cu(II) complex is detected following a proposed O-O cleavage event, that is suggested on the basis of precedent from non-heme iron chemistry. A bis-mu-oxo-dicopper(III) complex as active oxygenating agent is ruled out.

  DOI：

  10.1021/ja071704c