[Mn(II)(pivalate)2(EtOH)] | 852396-79-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: [Mn(II)(pivalate)2(EtOH)]
• CAS: 852396-79-3
• 化学式: C₁₂H₂₄MnO₅
• 分子量: 303.258
• InChiKey: FXFSYQKZCQTUEG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mn(II)(pivalate)2(EtOH)] 在 air 作用下， 以 乙醇 为溶剂， 以74%的产率得到[Mn6(μ-O)2(μ-pivalate)10(HOOCCMe3)(HOEt)3]*3EtOH
  参考文献：
  名称：

  New antiferromagnetic Mn(II) pivalate polymer: synthesis and reactivity

  摘要：

  An antiferromagnetic pivalate polymer complex [Mn(OOCCMe3)(2)(EtOH)](n) (1) has been prepared by the reaction between MnCl2 (.) 4H(2)O and KOOCCMe3 in EtOH. The reaction of 1 with 2,6-diaminopyridine (L) in MeCN resulted in an antiferromagnetic binuclear L2Mn2(mu-OOCCMe3)(4) (2) complex solvated with the four acetonitrile molecules. The oxidation of 1 was shown to give rise to a hexanuclear pivalate cluster Mn-6(mu(4)-O)(2)(mu-OOCCMe3)(10)(HOOCCMe3)(HOEt)(3) (3). Both the X-ray and the thermographic studies revealed low temperature phase transitions for 1 and 2. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.11.012
• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 乙醇 、 三甲基乙酸钾 以 乙醇 为溶剂， 以87%的产率得到[Mn(II)(pivalate)2(EtOH)]
  参考文献：
  名称：

  New antiferromagnetic Mn(II) pivalate polymer: synthesis and reactivity

  摘要：

  An antiferromagnetic pivalate polymer complex [Mn(OOCCMe3)(2)(EtOH)](n) (1) has been prepared by the reaction between MnCl2 (.) 4H(2)O and KOOCCMe3 in EtOH. The reaction of 1 with 2,6-diaminopyridine (L) in MeCN resulted in an antiferromagnetic binuclear L2Mn2(mu-OOCCMe3)(4) (2) complex solvated with the four acetonitrile molecules. The oxidation of 1 was shown to give rise to a hexanuclear pivalate cluster Mn-6(mu(4)-O)(2)(mu-OOCCMe3)(10)(HOOCCMe3)(HOEt)(3) (3). Both the X-ray and the thermographic studies revealed low temperature phase transitions for 1 and 2. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.11.012